Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.
A desymmetrization protocol has been used to develop a palladium catalyzed enantioselective carbonylation process. Achiral cyclic bis-alkenyltriflates are converted to their corresponding monoester derivatives with selectivities of up to 96% ee.
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2010
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| _version_ | 1797091445522300928 |
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| author | Byrne, S Fletcher, A Hebeisen, P Willis, M |
| author_facet | Byrne, S Fletcher, A Hebeisen, P Willis, M |
| author_sort | Byrne, S |
| collection | OXFORD |
| description | A desymmetrization protocol has been used to develop a palladium catalyzed enantioselective carbonylation process. Achiral cyclic bis-alkenyltriflates are converted to their corresponding monoester derivatives with selectivities of up to 96% ee. |
| first_indexed | 2024-03-07T03:33:11Z |
| format | Journal article |
| id | oxford-uuid:bb66351e-04b3-46a7-b49c-7ba35c2854ea |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:33:11Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:bb66351e-04b3-46a7-b49c-7ba35c2854ea2022-03-27T05:16:43ZEnantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:bb66351e-04b3-46a7-b49c-7ba35c2854eaEnglishSymplectic Elements at Oxford2010Byrne, SFletcher, AHebeisen, PWillis, MA desymmetrization protocol has been used to develop a palladium catalyzed enantioselective carbonylation process. Achiral cyclic bis-alkenyltriflates are converted to their corresponding monoester derivatives with selectivities of up to 96% ee. |
| spellingShingle | Byrne, S Fletcher, A Hebeisen, P Willis, M Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes. |
| title | Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes. |
| title_full | Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes. |
| title_fullStr | Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes. |
| title_full_unstemmed | Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes. |
| title_short | Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes. |
| title_sort | enantioselective desymmetrizing palladium catalyzed carbonylation reactions the catalytic asymmetric synthesis of quaternary carbon center containing 1 3 dienes |
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