Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.

A desymmetrization protocol has been used to develop a palladium catalyzed enantioselective carbonylation process. Achiral cyclic bis-alkenyltriflates are converted to their corresponding monoester derivatives with selectivities of up to 96% ee.

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Những tác giả chính: Byrne, S, Fletcher, A, Hebeisen, P, Willis, M
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 2010