PHOTOELECTRON-SPECTRA AND THEIR RELATIVISTIC INTERPRETATION FOR GASEOUS BISMUTH TRIHALIDES

Photoelectron spectra are reported for BiCl3, BiBr3 and BiI3. Assignments are obtained using the relativistically parameterized extended Hückel (REX) and perturbative Hartree-Fock-Slater methods. The halogen p-bands (4a1, 1a2, 4e, and 3e) resemble those in the lighter MX3 molecules at (M = P- Sb). T...

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Détails bibliographiques
Auteurs principaux: Egdell, R, Hotokka, M, Laaksonen, L, Pyykko, P, Snijders, J
Format: Journal article
Langue:English
Publié: 1982