PHOTOELECTRON-SPECTRA AND THEIR RELATIVISTIC INTERPRETATION FOR GASEOUS BISMUTH TRIHALIDES

Photoelectron spectra are reported for BiCl3, BiBr3 and BiI3. Assignments are obtained using the relativistically parameterized extended Hückel (REX) and perturbative Hartree-Fock-Slater methods. The halogen p-bands (4a1, 1a2, 4e, and 3e) resemble those in the lighter MX3 molecules at (M = P- Sb). T...

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Main Authors: Egdell, R, Hotokka, M, Laaksonen, L, Pyykko, P, Snijders, J
格式: Journal article
语言:English
出版: 1982