New environmentally friendly catalysts containing Pd-interstitial carbon made from Pd-glucose precursors for ultraselective hydrogenations in the liquid phase.
We report a novel preparation of a Pd nanocatalyst modified with subsurface C via blending a glucose precursor at the molecular level: the catalyst is demonstrated for the first time to be stereoselective in the hydrogenation of alkynes to cis-alkenes in the liquid phase.
Autori principali: | Chan, C, Xie, Y, Cailuo, N, Yu, K, Cookson, J, Bishop, P, Tsang, S |
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Natura: | Journal article |
Lingua: | English |
Pubblicazione: |
2011
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