Exploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexes
Sensitized luminescence from trivalent lanthanide ions relies on an appropriate energy match between the sensitizer’s excited state (triplet or singlet) and the lanthanide excited state manifold, and also an efficient mechanism of energy transfer between the two. Here, the effect of remote substitue...
| Main Authors: | , , , , , |
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| Format: | Journal article |
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Elsevier
2015
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| _version_ | 1797091558086934528 |
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| author | Tropiano, M Blackburn, O Tilney, J Hill, L Sørensen, T Faulkner, S |
| author_facet | Tropiano, M Blackburn, O Tilney, J Hill, L Sørensen, T Faulkner, S |
| author_sort | Tropiano, M |
| collection | OXFORD |
| description | Sensitized luminescence from trivalent lanthanide ions relies on an appropriate energy match between the sensitizer’s excited state (triplet or singlet) and the lanthanide excited state manifold, and also an efficient mechanism of energy transfer between the two. Here, the effect of remote substituents on the luminescence properties of a series of related lanthanide complexes has been investigated. The sensitized lanthanide centered emission is not invariably found to occur following excitation of all chromophores in all systems, and it is shown that only the most structurally congested of the systems investigated exhibited pronounced solvatochromism. |
| first_indexed | 2024-03-07T03:34:47Z |
| format | Journal article |
| id | oxford-uuid:bbea8580-ec5b-4f2c-a1a1-e279cbad153c |
| institution | University of Oxford |
| last_indexed | 2024-03-07T03:34:47Z |
| publishDate | 2015 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | oxford-uuid:bbea8580-ec5b-4f2c-a1a1-e279cbad153c2022-03-27T05:20:37ZExploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:bbea8580-ec5b-4f2c-a1a1-e279cbad153cSymplectic Elements at OxfordElsevier2015Tropiano, MBlackburn, OTilney, JHill, LSørensen, TFaulkner, SSensitized luminescence from trivalent lanthanide ions relies on an appropriate energy match between the sensitizer’s excited state (triplet or singlet) and the lanthanide excited state manifold, and also an efficient mechanism of energy transfer between the two. Here, the effect of remote substituents on the luminescence properties of a series of related lanthanide complexes has been investigated. The sensitized lanthanide centered emission is not invariably found to occur following excitation of all chromophores in all systems, and it is shown that only the most structurally congested of the systems investigated exhibited pronounced solvatochromism. |
| spellingShingle | Tropiano, M Blackburn, O Tilney, J Hill, L Sørensen, T Faulkner, S Exploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexes |
| title | Exploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexes |
| title_full | Exploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexes |
| title_fullStr | Exploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexes |
| title_full_unstemmed | Exploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexes |
| title_short | Exploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexes |
| title_sort | exploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexes |
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