Sodium hydride as a powerful reducing agent for topotactic oxide deintercalation: Synthesis and characterization of the nickel(I) oxide LaNiO2

Sodium hydride as a powerful reducing agent for topotactic oxide deintercalation: Synthesis and characterization of the nickel(I) oxide LaNiO2

The capability of sodium hydride as a reducing agent in oxide deintercalation reactions is explored. The Ni(III) perovskite LaNiO3 can be reduced topotactically to LaNiO2, isostructural with the 'infinite layer' cuprates, using solid sodium hydride in a sealed evacuated tube at 190 ≤ T/°C...

Полное описание

Библиографические подробности
Главные авторы:	Hayward, M, Green, M, Rosseinsky, M, Sloan, J
Формат:	Journal article
Язык:	English
Опубликовано:	1999

Схожие документы

Selective deintercalation of apex over face-shared oxide ions in the topotactic reduction of Sr7Mn4O15 to Sr7Mn4O12.
по: Hayward, M
Опубликовано: (2004)

Unraveling nano-scale effects of topotactic reduction in LaNiO2 crystals
по: Yu-Mi Wu, и др.
Опубликовано: (2024-09-01)

Synthesis of the infinite layer Ni(I) phase NdNiO2+x by low temperature reduction of NdNiO3 with sodium hydride
по: Hayward, M, и др.
Опубликовано: (2003)

Local Structure of Sodium- and Iron-deintercalated NaFeAs
по: Cassidy, S, и др.
Опубликовано: (2014)

Topotactic reduction of transition metal oxychlorides: A contrast to oxide chemistry
по: Dixon, E, и др.
Опубликовано: (2011)

Fingerprints of Topotactic Hydrogen in Nickelate Superconductors
по: Liang Si, и др.
Опубликовано: (2022-05-01)

Extensive hydrogen incorporation is not necessary for superconductivity in topotactically reduced nickelates
по: Purnima P. Balakrishnan, и др.
Опубликовано: (2024-08-01)

Comparison of topotactic fluorination methods for complex oxide films
по: E. J. Moon, и др.
Опубликовано: (2015-06-01)

Antiferromagnetic correlations in the metallic strongly correlated transition metal oxide LaNiO3
по: H. Guo, и др.
Опубликовано: (2018-01-01)

Electronic structure, magnetic ordering, and formation pathway of the transition metal oxide hydride LaSrCoO(3)H(0.7).
по: Bridges, C, и др.
Опубликовано: (2005)

Topotactic reduction of Y2Ti2O7
по: Hayward, M
Опубликовано: (2005)

Topotactic oxidative and reductive control of the structures and properties of layered manganese oxychalcogenides.
по: Hyett, G, и др.
Опубликовано: (2007)

On the Study of Ca and Mg Deintercalation from Ternary Tantalum Nitrides
по: Roberta Verrelli, и др.
Опубликовано: (2019-05-01)

Origin of a topotactic reduction effect for superconductivity in infinite-layer nickelates
по: Zeng, Shengwei, и др.
Опубликовано: (2024)

Layered CeSO and LiCeSO oxide chalcogenides obtained via topotactic oxidative and reductive transformations
по: Cassidy, S, и др.
Опубликовано: (2019)

Lithium aluminum hydride as reducing agent for chemically reduced graphene oxides
по: Ambrosi, Adriano, и др.
Опубликовано: (2013)

The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7.
по: Hayward, M, и др.
Опубликовано: (2002)

Metal-insulator-superconductor transition in nickelate-based heterostructures driven by topotactic reduction
по: Han, Kun, и др.
Опубликовано: (2024)

LaSr3NiRuO4H4: a 4d transition-metal oxide-hydride containing metal hydride sheets
по: Jin, L, и др.
Опубликовано: (2018)

Topotactic reduction of YBaCo2O5 and LaBaCo2O5: square-planar Co(I) in an extended oxide.
по: Seddon, J, и др.
Опубликовано: (2010)

Dearylation of arylphosphine oxides using a sodium hydride–iodide composite
по: Tejo, Ciputra, и др.
Опубликовано: (2019)

Influence of Topotactic Reduction on the Structure and Magnetism of the Multiferroic YMnO3
по: Overton, A, и др.
Опубликовано: (2009)

Breathing distortions in the metallic, antiferromagnetic phase of LaNiO$_3$
по: Alaska Subedi
Опубликовано: (2018-09-01)

Vibrational properties of LaNiO3 films in the ultrathin regime
по: Alexander Schober, и др.
Опубликовано: (2020-06-01)

Electronic structure of buried LaNiO3 layers in (111)-oriented LaNiO3/LaMnO3 superlattices probed by soft x-ray ARPES
по: F. Y. Bruno, и др.
Опубликовано: (2017-01-01)

Phase separation during the topotactic reduction of the pyrochlore Y2Ti2O7
по: Hayward, M
Опубликовано: (2005)

Improved conduction and orbital polarization in ultrathin LaNiO3 sublayer by modulating octahedron rotation in LaNiO3/CaTiO3 superlattices
по: Wenxiao Shi, и др.
Опубликовано: (2024-11-01)

Structure and magnetism of the topotactically reduced oxychloride Sr4Mn3O(6.5)Cl2.
по: Romero, F, и др.
Опубликовано: (2012)

Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids
по: Jin, L, и др.
Опубликовано: (2019)

Magnetism in oxide chains bridged with the hydride anion: LaSrCoO3H0.7 studied using muon-spin rotation
по: Blundell, S, и др.
Опубликовано: (2003)

Platinum nanosheets synthesized via topotactic reduction of single-layer platinum oxide nanosheets for electrocatalysis
по: Daisuke Takimoto, и др.
Опубликовано: (2023-01-01)

Promoting biomass electrooxidation via modulating proton and oxygen anion deintercalation in hydroxide
по: Zuyun He, и др.
Опубликовано: (2022-06-01)

Recovery Of Electrodic Powder From Spent Nickel-Metal Hydride Batteries (NiMH)
по: Shin S.M., и др.
Опубликовано: (2015-06-01)

Observation of an antiferromagnetic quantum critical point in high-purity LaNiO3
по: Changjiang Liu, и др.
Опубликовано: (2020-03-01)

Strontium vanadium oxide-hydrides: "square-planar" two-electron phases.
по: Denis Romero, F, и др.
Опубликовано: (2014)

Research Update: Orbital polarization in LaNiO3-based heterostructures
по: Ankit S. Disa, и др.
Опубликовано: (2015-06-01)

Topotactic reduction as a synthetic route for the preparation of low-dimensional Mn(II) oxide phases: the structure and magnetism of LaAMnO(4-x) (A = Sr, Ba).
по: Kitchen, H, и др.
Опубликовано: (2010)

METHANE PARTIAL OXIDATION BY THE LATTICE OXYGEN OF THE LANIO3d PEROVSKITE. A PULSE STUDY
по: GERMÁN SIERRA GALLEGO, и др.
Опубликовано: (2010-01-01)

Hydride Reduction by a Sodium Hydride-Iodide Composite
по: Too, Pei Chui, и др.
Опубликовано: (2017)

Emergence of Dynamically‐Disordered Phases During Fast Oxygen Deintercalation Reaction of Layered Perovskite
по: Takafumi Yamamoto, и др.
Опубликовано: (2023-07-01)