Sodium hydride as a powerful reducing agent for topotactic oxide deintercalation: Synthesis and characterization of the nickel(I) oxide LaNiO2

Sodium hydride as a powerful reducing agent for topotactic oxide deintercalation: Synthesis and characterization of the nickel(I) oxide LaNiO2

The capability of sodium hydride as a reducing agent in oxide deintercalation reactions is explored. The Ni(III) perovskite LaNiO3 can be reduced topotactically to LaNiO2, isostructural with the 'infinite layer' cuprates, using solid sodium hydride in a sealed evacuated tube at 190 ≤ T/°C...

書目詳細資料
Main Authors:	Hayward, M, Green, M, Rosseinsky, M, Sloan, J
格式:	Journal article
語言:	English
出版:	1999

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