High-temperature-phase Bi4RhI2: electronic localization by structural distortion
The metal-rich compound Bi4RhI2 was discovered in a thorough investigation of the Bi-Rh-I phase system. The monoclinic crystal structure was solved via single-crystal X-ray diffraction. It consists of infinite strands of face-sharing distorted square antiprisms ∞1[RhBi8/2]2+, which are separated by...
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| Médium: | Journal article |
| Jazyk: | English |
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American Chemical Society
2018
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