High-temperature-phase Bi4RhI2: electronic localization by structural distortion
The metal-rich compound Bi4RhI2 was discovered in a thorough investigation of the Bi-Rh-I phase system. The monoclinic crystal structure was solved via single-crystal X-ray diffraction. It consists of infinite strands of face-sharing distorted square antiprisms ∞1[RhBi8/2]2+, which are separated by...
| Main Authors: | , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2018
|