High-temperature-phase Bi4RhI2: electronic localization by structural distortion

The metal-rich compound Bi4RhI2 was discovered in a thorough investigation of the Bi-Rh-I phase system. The monoclinic crystal structure was solved via single-crystal X-ray diffraction. It consists of infinite strands of face-sharing distorted square antiprisms ∞1[RhBi8/2]2+, which are separated by...

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Detalhes bibliográficos
Principais autores: Rasche, B, Ruck, M
Formato: Journal article
Idioma:English
Publicado em: American Chemical Society 2018