REGIOSPECIFIC AND STEREOSPECIFIC SYNTHESIS OF CIS-(+/-)-1-ACETOXY-4-(ACETOXYMETHYL)CYCLOPENT-2-ENE - A KEY INTERMEDIATE IN THE SYNTHESIS OF CARBOCYCLIC NUCLEOSIDES AND PSEUDO-RIBOFURANOSES
The synthesis of cis-(±)-1-acetoxy-4-(acetoxymethyl)cyclopent-2-ene 1 from cyclopent-3-ene-1-carboxylic acid 2 by way of bromolactonisation, reductive ring opening and diacylation with in situ elimination of HBr is described.
Main Authors: | , , |
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Format: | Journal article |
Language: | English |
Published: |
1993
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Summary: | The synthesis of cis-(±)-1-acetoxy-4-(acetoxymethyl)cyclopent-2-ene 1 from cyclopent-3-ene-1-carboxylic acid 2 by way of bromolactonisation, reductive ring opening and diacylation with in situ elimination of HBr is described. |
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