Synthesis and rac-lactide ring-opening polymerisation studies of new alkaline earth tetrahydroborate complexes.
Reaction of K[HC(C(Me)NAr')(2)] (Ar' = 2,6-C(6)H(3)(i)Pr(2)) with Mg(BH(4))(2) afforded the pseudo four-coordinate tetrahydroborate complex Mg{HC(C(Me)NAr')(2)}(BH(4))(THF) (1). The corresponding reaction of Ca(BH(4))(2)(THF)(2) or Sr(BH(4))(2)(THF)(2) gave the pseudo five-coordinate...
| Main Authors: | , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2013
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