Crystal structure and magnetic modulation in beta-Ce2O2FeSe2
We report a combination of X-ray and neutron diffraction studies, Mössbauer spectroscopy and muon spin relaxation (μ+SR) measurements to probe the structure and magnetic properties of the semiconducting β-Ce2O2FeSe2 oxychalcogenide. We report a new structural description in space group Pna21 which i...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
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American Physical Society
2017
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| _version_ | 1826294011043774464 |
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| author | Wang, C Ainsworth, C Champion, S Stewart, G Worsdale, M Lancaster, T Blundell, S Brand, H Evans, J |
| author_facet | Wang, C Ainsworth, C Champion, S Stewart, G Worsdale, M Lancaster, T Blundell, S Brand, H Evans, J |
| author_sort | Wang, C |
| collection | OXFORD |
| description | We report a combination of X-ray and neutron diffraction studies, Mössbauer spectroscopy and muon spin relaxation (μ+SR) measurements to probe the structure and magnetic properties of the semiconducting β-Ce2O2FeSe2 oxychalcogenide. We report a new structural description in space group Pna21 which is consistent with diffraction data and second harmonic generation measurements and reveal an order-disorder transition on one Fe site at TOD ≈ 330 K. Susceptibility measurements, Mössbauer and μ+SR reveal antiferromagnetic ordering below TN = 86 K and more complex short range order above this temperature. 12 K neutron diffraction data reveal a modulated magnetic structure with q = 0.444 bN* |
| first_indexed | 2024-03-07T03:39:02Z |
| format | Journal article |
| id | oxford-uuid:bd41ea6c-6bbb-4599-9790-1bd3e928a2ac |
| institution | University of Oxford |
| last_indexed | 2024-03-07T03:39:02Z |
| publishDate | 2017 |
| publisher | American Physical Society |
| record_format | dspace |
| spelling | oxford-uuid:bd41ea6c-6bbb-4599-9790-1bd3e928a2ac2022-03-27T05:30:25ZCrystal structure and magnetic modulation in beta-Ce2O2FeSe2Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:bd41ea6c-6bbb-4599-9790-1bd3e928a2acSymplectic Elements at OxfordAmerican Physical Society2017Wang, CAinsworth, CChampion, SStewart, GWorsdale, MLancaster, TBlundell, SBrand, HEvans, JWe report a combination of X-ray and neutron diffraction studies, Mössbauer spectroscopy and muon spin relaxation (μ+SR) measurements to probe the structure and magnetic properties of the semiconducting β-Ce2O2FeSe2 oxychalcogenide. We report a new structural description in space group Pna21 which is consistent with diffraction data and second harmonic generation measurements and reveal an order-disorder transition on one Fe site at TOD ≈ 330 K. Susceptibility measurements, Mössbauer and μ+SR reveal antiferromagnetic ordering below TN = 86 K and more complex short range order above this temperature. 12 K neutron diffraction data reveal a modulated magnetic structure with q = 0.444 bN* |
| spellingShingle | Wang, C Ainsworth, C Champion, S Stewart, G Worsdale, M Lancaster, T Blundell, S Brand, H Evans, J Crystal structure and magnetic modulation in beta-Ce2O2FeSe2 |
| title | Crystal structure and magnetic modulation in beta-Ce2O2FeSe2 |
| title_full | Crystal structure and magnetic modulation in beta-Ce2O2FeSe2 |
| title_fullStr | Crystal structure and magnetic modulation in beta-Ce2O2FeSe2 |
| title_full_unstemmed | Crystal structure and magnetic modulation in beta-Ce2O2FeSe2 |
| title_short | Crystal structure and magnetic modulation in beta-Ce2O2FeSe2 |
| title_sort | crystal structure and magnetic modulation in beta ce2o2fese2 |
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