An asymmetrically derivatized 1,2,3-triphospholide: synthesis and reactivity of the 4-(2'-pyridyl)-1,2,3-triphospholide anion.
Reactions between anionic heptaphosphide clusters ([P7](3-)/[HP7](2-)) and 2-ethynylpyridine yielded the 4-(2'-pyridyl)-1,2,3-triphospholide anion ([P3C2H(2-C5H4N)](-); 1). This species was isolated as a compositionally pure [K(2,2,2-crypt)](+) salt in moderate yields. Preliminary coordination...
| Autori principali: | , |
|---|---|
| Natura: | Journal article |
| Lingua: | English |
| Pubblicazione: |
2013
|