Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: Evidence for solubilisation via a proton dissociation-recombination mechanism
Quantitative Atomic Force Microscopy measurements made on the dissolving surface of solid salicylic acid in H2O and D2O reveal a kinetic isotope effect (kH/kD = 2.3 ± 0.6) on the dissolution rate consistent with a transition state in which the proton is dissociated from the dissolving molecule.
| Κύριοι συγγραφείς: | , , |
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| Μορφή: | Journal article |
| Γλώσσα: | English |
| Έκδοση: |
2002
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| _version_ | 1826294066420121600 |
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| author | Wilkins, S Coles, B Compton, R |
| author_facet | Wilkins, S Coles, B Compton, R |
| author_sort | Wilkins, S |
| collection | OXFORD |
| description | Quantitative Atomic Force Microscopy measurements made on the dissolving surface of solid salicylic acid in H2O and D2O reveal a kinetic isotope effect (kH/kD = 2.3 ± 0.6) on the dissolution rate consistent with a transition state in which the proton is dissociated from the dissolving molecule. |
| first_indexed | 2024-03-07T03:39:54Z |
| format | Journal article |
| id | oxford-uuid:bd89c2af-3e74-443e-a31d-ada4d5d617ae |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:39:54Z |
| publishDate | 2002 |
| record_format | dspace |
| spelling | oxford-uuid:bd89c2af-3e74-443e-a31d-ada4d5d617ae2022-03-27T05:32:30ZKinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: Evidence for solubilisation via a proton dissociation-recombination mechanismJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:bd89c2af-3e74-443e-a31d-ada4d5d617aeEnglishSymplectic Elements at Oxford2002Wilkins, SColes, BCompton, RQuantitative Atomic Force Microscopy measurements made on the dissolving surface of solid salicylic acid in H2O and D2O reveal a kinetic isotope effect (kH/kD = 2.3 ± 0.6) on the dissolution rate consistent with a transition state in which the proton is dissociated from the dissolving molecule. |
| spellingShingle | Wilkins, S Coles, B Compton, R Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: Evidence for solubilisation via a proton dissociation-recombination mechanism |
| title | Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: Evidence for solubilisation via a proton dissociation-recombination mechanism |
| title_full | Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: Evidence for solubilisation via a proton dissociation-recombination mechanism |
| title_fullStr | Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: Evidence for solubilisation via a proton dissociation-recombination mechanism |
| title_full_unstemmed | Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: Evidence for solubilisation via a proton dissociation-recombination mechanism |
| title_short | Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: Evidence for solubilisation via a proton dissociation-recombination mechanism |
| title_sort | kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution evidence for solubilisation via a proton dissociation recombination mechanism |
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