Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: Evidence for solubilisation via a proton dissociation-recombination mechanism
Quantitative Atomic Force Microscopy measurements made on the dissolving surface of solid salicylic acid in H2O and D2O reveal a kinetic isotope effect (kH/kD = 2.3 ± 0.6) on the dissolution rate consistent with a transition state in which the proton is dissociated from the dissolving molecule.
প্রধান লেখক: | Wilkins, S, Coles, B, Compton, R |
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বিন্যাস: | Journal article |
ভাষা: | English |
প্রকাশিত: |
2002
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অনুরূপ উপাদানগুলি
অনুরূপ উপাদানগুলি
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Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: evidence for solubilisation via a proton dissociation-recombination mechanism.
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প্রকাশিত: (2002) -
A hydrodynamic atomic force microscopy flow cell for the quantitative measurement of interfacial kinetics: The aqueous dissolution of salicylic acid and calcium carbonate
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প্রকাশিত: (1998) -
Mechanism and kinetics of salicylic acid dissolution in aqueous solution under defined hydrodynamic conditions via atomic force microscopy: The effects of the ionic additives NaCl, LiCl and MgCl2, the organic additives 1-propanol, 2-propanol, and the surfactant sodium dodecyl sulfate
অনুযায়ী: Wilkins, S, অন্যান্য
প্রকাশিত: (2002) -
The Dissolution of Calcite in Aqueous-Solution at PH <4 :Kinetics and Mechanism
অনুযায়ী: Compton, R, অন্যান্য
প্রকাশিত: (1990) -
The effect of surface pretreatment with polymaleic acid, phosphoric acid, or oxalic acid on the dissolution kinetics of calcium carbonate in aqueous acid
অনুযায়ী: Wilkins, S, অন্যান্য
প্রকাশিত: (2001)