(ETA-5-C5H5)RU(PPH3)H3 - A STABLE RUTHENIUM(IV) TRIHYDRIDE

(ETA-5-C5H5)RU(PPH3)H3 - A STABLE RUTHENIUM(IV) TRIHYDRIDE

Bibliografske podrobnosti
Main Authors:	Davies, S, Moon, S, Simpson, S
Format:	Journal article
Izdano:	1983

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BIMETALLIC CYANO-BRIDGED CATIONS - PREPARATION AND HYDRIDE REDUCTION OF [(ETA-5-C5H5)L2RU(MU-CN)ML'2(ETA-5-C5H5)]PF6[L2,L'2=(PPH3)2,PH2PCH2CH2PPH2 - M = RU OR FE] - FORMATION OF [RU(ETA-5-C5H5)(PPH3)H3] AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)(PH2PCH2CH2PPH2)RU(MU-CN)RU(PPH3)2(ETA-5-C5H5)]PF6
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A CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3]
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ELECTRON-RICH CATIONS - PREPARATION AND HYDRIDE REDUCTIONS OF THE CATIONS ((ETA-5-C5H5)RU[MEC(CH2PPH2)3])+ AND "((ETA-5-C5H5)RU[PHP(CH2CH2PPH2)2])+
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HYDRIDE ADDITION TO THE CATIONS [( ETA-5-C5H5)RU(L)2CO]+ (L=PPH3, L2=PH2PCH2CH2PPH2)
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STEREOSELECTIVE ADDITIONS TO THE ALKOXYCARBENE CATIONS [ETA-5-C5H5)FE(CO)(PPH3)(=CHOME)], [ETA-5-C5H5)FE(CO)(PPH3)(=CETOME)]
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FRAGMENTATION OF (ETA-5-C5H5)FE(CO)(PPH3)(COCH2COR) COMPLEXES TO THE CATION [(ETA-5-C5H5)FE(CO)2(PPH3)]+
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CHEMISTRY OF (ETA-5-C5H5)RU(PH2PCH2CH2PPH2)CL - PREPARATION OF CATIONIC RUTHENIUM OLEFIN COMPLEXES
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ELECTRON-RICH CATIONS - PREPARATION AND HYDRIDE REDUCTIONS OF THE CATIONS [FE(ETA-5-C5H5)(PHP(CH2CH2PPH2)2)]+, [FE(ETA-5-C5H5)(MEC(CH2PPH2)3)]+, AND [FE(ETA-5-C5H5)(C(CH2PPH2)4)]+
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CONFORMATION-REACTIVITY RELATIONSHIPS FOR THE ORGANOTRANSITION-METAL COMPLEXES (ETA-5-C5H5)FE(CO)(PPH3)R AND (ETA-5-C5H5)RE(NO)(PPH3)R (R = ALKYL AND ARYL)
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CONFORMATION ANALYSIS OF COMPOUNDS OF THE TYPE [FE(ETA-5-C5H5)(CO)(PPH3)(CH2ALKYL)], "[FE(ETA-5-C5H5)(CO)(PPH3)(CH2ARYL)] - REPLY
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SELF-RECOGNITION BY THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)] IN THE FORMATION OF (RR,SS)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2]2CH2
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REGIOSELECTIVITY OF HYDRIDE ADDITION TO [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 AND REARRANGEMENT OF "(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)(CO)H TO (ETA-4-C5H6)FE(PH2PCH2CH2PPH2)CO
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THE STEREOSELECTIVE NUCLEOPHILIC-ADDITION OF CYANIDE TO THE CATIONIC RUTHENIUM COMPLEXES [(ETA-5-C5H5)L2RU=C=C(ME)PH]+ (L2 = (PME3)2 OR (PPH2CH2)2)
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HYDRIDE REDUCTION OF THE CATION [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
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HYDRIDE REDUCTION OF THE CATION [ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
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STEREOSELECTIVE ELABORATION OF THE ACYL LIGAND IN (ETA-5-C5H5)FE(CO)(PPH3)(COCH2R) VIA THE ALKYLATION OF THE ANIONS "[(ETA-5-C5H5)FE(CO)(PPH3)(COCHR)]LI (R = ME, ET)
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ASYMMETRIC-SYNTHESIS VIA THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]
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DISPROPORTIONATION OF THE IRON CARBONYL HYDRIDE "(ETA-5-C5H5)FE(CO)H(PH2PCH2CH2PPH2) TO THE IRON METHYL (ETA-5-C5H5)FE(PH2PCH2CH2PPH2)ME
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CONFORMATIONAL-ANALYSIS AND DYNAMICS OF THE TRIPHENYLPHOSPHINE LIGAND IN [(ETA-5-C5H5)FE(CO)(PPH3)COCH3]
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STEREOCHEMICAL CONTROL AND MECHANISTIC ASPECTS OF THE ALKYLATION OF [(ETA-5-C5H5)FE(PPH3,PPH2NET2)(CO)(COCH(ME)ET)]-LI+ - X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(PPH3)(CO)(COCH(ME)ET)]
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PREPARATION AND REACTIVITY OF THE ANION "[(ETA-5-C5H5)FE(CO)(PPH3)(COCH2)]LI
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HYDRIDE REDUCTION OF THE CATIONS "((ETA-5-C5H5)FE[(PH2PCH2)3CME])PF6, ((ETA-5-C5H5)-RU[(PH2PCH2CH2)2PPH])PF6, AND ((ETA-5-C5H5)RU[PH2PCH2)3CME])PF6 - REGIOSELECTIVITY AND MECHANISM
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THE STEREOSELECTIVE REACTION OF SODIUM-CYANIDE WITH THE CATIONIC RUTHENIUM VINYLIDENE COMPLEX [(ETA-5-C5H5)(PME3)2RU=C=C(ME)PH]+
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THE ASYMMETRIC SYNTHESIS OF (-)-ACTINONIN USING THE IRON CHIRAL AUXILIARY [(ETA5-C5H5)FE(CO)(PPH3)]
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THE ASYMMETRIC-SYNTHESIS OF (-)-CAPTOPRIL UTILIZING THE IRON CHIRAL AUXILIARY [ETA-5-C5H5)FE(CO)(PPH3)]
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DETERMINATION OF THE ABSOLUTE-CONFIGURATION AND OPTICAL PURITY OF [(ETA-5-C5H5)FE(CO)(PPH3)COME] - X-RAY CRYSTAL-STRUCTURE OF (R)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2CH2O[(R)-MENTHYL]]
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EVIDENCE FOR THE IRON FORMYL "(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)(CHO)
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ASYMMETRIC-SYNTHESIS OF (1R,8S)-1-HYDROXYPYRROLIZIDIN-3-ONE AND (1S,8S)-1-HYDROXYPYRROLIZIDIN-3-ONE FROM BOC-L-PROLINAL AND (S)-[(ETA-5-C5H5)FE(CO)(PPH3)(AC)] AND (R)-[(ETA-5-C5H5)FE(CO)(PPH3)(AC)], RESPECTIVELY
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A NOVEL ONE-POT SYNTHESIS OF HOMOCHIRAL (R)-(-) AND (S)-(+)-FE(CO)(ETA(5)-C5H5)(PPH(3))COCH3
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CARBON-MONOXIDE REDUCTION - [FE(ETA-5-C5H5)(PH2PCH2CH2PPH2)(CO)H] - REACTIONS AND FORMATION BY REDUCTION OF THE COMPLEX [FE(ETA-5-C5H5)(PH2PCH2CH2PPH2)(CO)]PF6
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CONFORMATIONAL-ANALYSIS FOR THE ALKYL LIGANDS(R) IN COMPLEXES OF THE TYPE(ETA-5-C5H5]FE(CO)(PPH3)R
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STEREOSPECIFICITY OF THE REARRANGEMENT OF THE ALPHA-ALKOXY IRON ACYL [(ETA-5-C5H5)FE(CO)(PPH3)COCH2OCH2PH] TO THE ALPHA-METALLA-ESTER [(ETA-5-C5H5)FE(CO)(PPH3)CH2CO2CH2PH]
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FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)]
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CONFORMATIONAL-ANALYSIS FOR THE PSEUDO-OCTAHEDRAL COMPLEXES - [(ETA-5-C5H5)FE(CO)-(PPH3)CH2R
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ELABORATION OF ACYL LIGANDS - PREPARATION AND REACTIVITY OF THE ANION [ETA-5-C5H5)FE(CO)(PPH3)(COCH2)]-
od: Aktogu, N, et al.
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STEREOSELECTIVE CARBON CARBON BOND FORMATION VIA ALKYLATION OF [(ETA-5-C5H5)FE(PPH3)(CO)(COME=CHR)] (R=ME,PRN,PH) - X-RAY CRYSTAL-STRUCTURE OF (Z)-[(ETA-5-C5H5)FE(PPH3)(CO)(COME=CHME)]
od: Baird, G, et al.
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CHIRAL DIENOLATES - FORMATION AND STEREOSELECTIVE ALPHA-ALKYLATION OF THE LITHIUM DIENOLATE DERIVED FROM (Z)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME] - X-RAY CRYSTAL-STRUCTURE OF (RS)-(Z)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME]
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CONTRASTING LIGAND PHOTOLABILISATIONS IN THE ACETYL COMPLEXES [(ETA(5)-C(5)R(5))FE(CO)(PPH(3))COME] (R=H, ME)
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CONFORMATIONAL-ANALYSIS AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(CO)(PPH3)CH2CH3]
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CONFORMATIONAL-ANALYSIS AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(CO)PPH3)CH2SIME3]
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