A CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3]
Treatment of [Ru(η-C5H5)(PPh3)2Cl] with sulphur under carbon monoxide at 1-3 atm in hot toluene gives quantitative yields of [Ru(η-C5H5)(PPh3)(CO)Cl], which can be further treated in warm methanol with CO, PMe3, and P(OPh)3 to give the cations [Ru(ηC5H5)(PPh3)(CO)2] +, [Ru(η-C5H5)(PPh3)(PMe 3)(CO)]+...
| Main Authors: | , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
1984
|
| _version_ | 1797092093841113088 |
|---|---|
| author | Davies, S Simpson, S |
| author_facet | Davies, S Simpson, S |
| author_sort | Davies, S |
| collection | OXFORD |
| description | Treatment of [Ru(η-C5H5)(PPh3)2Cl] with sulphur under carbon monoxide at 1-3 atm in hot toluene gives quantitative yields of [Ru(η-C5H5)(PPh3)(CO)Cl], which can be further treated in warm methanol with CO, PMe3, and P(OPh)3 to give the cations [Ru(ηC5H5)(PPh3)(CO)2] +, [Ru(η-C5H5)(PPh3)(PMe 3)(CO)]+, and [Ru(η-C5H5)(PPh3){P(OPh) 3}(CO)]+ respectively. |
| first_indexed | 2024-03-07T03:41:26Z |
| format | Journal article |
| id | oxford-uuid:be06e8b0-80ed-492b-aede-2df5aa665836 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:41:26Z |
| publishDate | 1984 |
| record_format | dspace |
| spelling | oxford-uuid:be06e8b0-80ed-492b-aede-2df5aa6658362022-03-27T05:36:13ZA CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3]Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:be06e8b0-80ed-492b-aede-2df5aa665836EnglishSymplectic Elements at Oxford1984Davies, SSimpson, STreatment of [Ru(η-C5H5)(PPh3)2Cl] with sulphur under carbon monoxide at 1-3 atm in hot toluene gives quantitative yields of [Ru(η-C5H5)(PPh3)(CO)Cl], which can be further treated in warm methanol with CO, PMe3, and P(OPh)3 to give the cations [Ru(ηC5H5)(PPh3)(CO)2] +, [Ru(η-C5H5)(PPh3)(PMe 3)(CO)]+, and [Ru(η-C5H5)(PPh3){P(OPh) 3}(CO)]+ respectively. |
| spellingShingle | Davies, S Simpson, S A CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3] |
| title | A CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3] |
| title_full | A CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3] |
| title_fullStr | A CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3] |
| title_full_unstemmed | A CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3] |
| title_short | A CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3] |
| title_sort | convenient synthesis of ru eta c5h5 pph3 co cl and the cations ru eta c5h5 pph3 l co l co pme3 or p oph 3 |
| work_keys_str_mv | AT daviess aconvenientsynthesisofruetac5h5pph3coclandthecationsruetac5h5pph3lcolcopme3orpoph3 AT simpsons aconvenientsynthesisofruetac5h5pph3coclandthecationsruetac5h5pph3lcolcopme3orpoph3 AT daviess convenientsynthesisofruetac5h5pph3coclandthecationsruetac5h5pph3lcolcopme3orpoph3 AT simpsons convenientsynthesisofruetac5h5pph3coclandthecationsruetac5h5pph3lcolcopme3orpoph3 |