SYNTHESIS OF 1-EPIHYDANTOCIDIN FROM D-RIBOSE
A key step in a short synthesis of 1-epihydantocidin (2) is the unanticipated transformation of azidolactones (8) and (10) to a bicyclic amine (12) induced by tetra-n-propylammonium perruthenate in the presence of morpholine-N-oxide. The structure of (12) was established by X-ray crystallographic an...
| Main Authors: | , , , |
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| Format: | Journal article |
| Published: |
1993
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| Summary: | A key step in a short synthesis of 1-epihydantocidin (2) is the unanticipated transformation of azidolactones (8) and (10) to a bicyclic amine (12) induced by tetra-n-propylammonium perruthenate in the presence of morpholine-N-oxide. The structure of (12) was established by X-ray crystallographic analysis. © 1993. |
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