Photophysics of threaded sp-carbon chains: the polyyne is a sink for singlet and triplet excitation.
We have used single-crystal X-ray diffraction and time-resolved UV-NIR-IR absorption spectroscopy to gain insights into the structures and excited-state dynamics of a rotaxane consisting of a hexayne chain threaded through a phenanthroline macrocycle and a family of related compounds, including the...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2014
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