Tetrahydrofuran alpha-azido esters: Precursors of anomeric alpha-amino acid monomers via radical bromination
A general route for the synthesis of tetrahydrofuran α-azido esters as the equivalent of monomeric furanose anomeric α-amino acids is described. Highly selective radical bromination of a range of suitably protected carbohydrate C-glycosyl derivatives affords bromo-esters which undergo efficient disp...
| Asıl Yazarlar: | , , , , , |
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| Materyal Türü: | Journal article |
| Dil: | English |
| Baskı/Yayın Bilgisi: |
1999
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| _version_ | 1826294385231265792 |
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| author | Smith, M Long, D Martin, A Campbell, N Bleriot, Y Fleet, G |
| author_facet | Smith, M Long, D Martin, A Campbell, N Bleriot, Y Fleet, G |
| author_sort | Smith, M |
| collection | OXFORD |
| description | A general route for the synthesis of tetrahydrofuran α-azido esters as the equivalent of monomeric furanose anomeric α-amino acids is described. Highly selective radical bromination of a range of suitably protected carbohydrate C-glycosyl derivatives affords bromo-esters which undergo efficient displacement by azide to give anomeric α-amino acid derivatives. |
| first_indexed | 2024-03-07T03:44:49Z |
| format | Journal article |
| id | oxford-uuid:bf1c3bcb-2b14-475d-ae29-1eaa3a05cb7c |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:44:49Z |
| publishDate | 1999 |
| record_format | dspace |
| spelling | oxford-uuid:bf1c3bcb-2b14-475d-ae29-1eaa3a05cb7c2022-03-27T05:44:54ZTetrahydrofuran alpha-azido esters: Precursors of anomeric alpha-amino acid monomers via radical brominationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:bf1c3bcb-2b14-475d-ae29-1eaa3a05cb7cEnglishSymplectic Elements at Oxford1999Smith, MLong, DMartin, ACampbell, NBleriot, YFleet, GA general route for the synthesis of tetrahydrofuran α-azido esters as the equivalent of monomeric furanose anomeric α-amino acids is described. Highly selective radical bromination of a range of suitably protected carbohydrate C-glycosyl derivatives affords bromo-esters which undergo efficient displacement by azide to give anomeric α-amino acid derivatives. |
| spellingShingle | Smith, M Long, D Martin, A Campbell, N Bleriot, Y Fleet, G Tetrahydrofuran alpha-azido esters: Precursors of anomeric alpha-amino acid monomers via radical bromination |
| title | Tetrahydrofuran alpha-azido esters: Precursors of anomeric alpha-amino acid monomers via radical bromination |
| title_full | Tetrahydrofuran alpha-azido esters: Precursors of anomeric alpha-amino acid monomers via radical bromination |
| title_fullStr | Tetrahydrofuran alpha-azido esters: Precursors of anomeric alpha-amino acid monomers via radical bromination |
| title_full_unstemmed | Tetrahydrofuran alpha-azido esters: Precursors of anomeric alpha-amino acid monomers via radical bromination |
| title_short | Tetrahydrofuran alpha-azido esters: Precursors of anomeric alpha-amino acid monomers via radical bromination |
| title_sort | tetrahydrofuran alpha azido esters precursors of anomeric alpha amino acid monomers via radical bromination |
| work_keys_str_mv | AT smithm tetrahydrofuranalphaazidoestersprecursorsofanomericalphaaminoacidmonomersviaradicalbromination AT longd tetrahydrofuranalphaazidoestersprecursorsofanomericalphaaminoacidmonomersviaradicalbromination AT martina tetrahydrofuranalphaazidoestersprecursorsofanomericalphaaminoacidmonomersviaradicalbromination AT campbelln tetrahydrofuranalphaazidoestersprecursorsofanomericalphaaminoacidmonomersviaradicalbromination AT blerioty tetrahydrofuranalphaazidoestersprecursorsofanomericalphaaminoacidmonomersviaradicalbromination AT fleetg tetrahydrofuranalphaazidoestersprecursorsofanomericalphaaminoacidmonomersviaradicalbromination |