Synthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3− (M = Nb, Ta) from binary [M@As8]3− precursors
<p>The development of rational synthetic routes to inorganic arsenide compounds is an important goal because these materials are finding applications in many areas of materials science. In this paper, we show that the binary crown clusters [M@As<small><sub>8</sub></small&g...
| Main Authors: | , , , |
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| פורמט: | Journal article |
| שפה: | English |
| יצא לאור: |
Royal Society of Chemistry
2022
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| _version_ | 1826309822043127808 |
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| author | Zhang, W-Q Morgan, HWT McGrady, JE Sun, Z-M |
| author_facet | Zhang, W-Q Morgan, HWT McGrady, JE Sun, Z-M |
| author_sort | Zhang, W-Q |
| collection | OXFORD |
| description | <p>The development of rational synthetic routes to inorganic arsenide compounds is an important goal because these materials are finding applications in many areas of materials science. In this paper, we show that the binary crown clusters [M@As<small><sub>8</sub></small>]<small><sup>3−</sup></small> (M = Nb, Ta) can be used as synthetic precursors which, when combined with ZnMes<small><sub>2</sub></small>, generate ternary intermetalloid clusters with 12-vertex cages, {M@[As<small><sub>8</sub></small>(ZnMes)<small><sub>4</sub></small>]}<small><sup>3−</sup></small> (M = Nb, Ta). Structural studies are complemented by mass spectrometry and an analysis of the electronic structure using DFT. The synthesis of these clusters presents new opportunities for the construction of As-based nanomaterials.</p> |
| first_indexed | 2024-03-07T07:41:26Z |
| format | Journal article |
| id | oxford-uuid:bf27d0f1-17e7-4207-b2fb-0864b5a7e11d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T07:41:26Z |
| publishDate | 2022 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:bf27d0f1-17e7-4207-b2fb-0864b5a7e11d2023-04-21T12:22:28ZSynthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3− (M = Nb, Ta) from binary [M@As8]3− precursorsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:bf27d0f1-17e7-4207-b2fb-0864b5a7e11dEnglishSymplectic ElementsRoyal Society of Chemistry2022Zhang, W-QMorgan, HWTMcGrady, JESun, Z-M<p>The development of rational synthetic routes to inorganic arsenide compounds is an important goal because these materials are finding applications in many areas of materials science. In this paper, we show that the binary crown clusters [M@As<small><sub>8</sub></small>]<small><sup>3−</sup></small> (M = Nb, Ta) can be used as synthetic precursors which, when combined with ZnMes<small><sub>2</sub></small>, generate ternary intermetalloid clusters with 12-vertex cages, {M@[As<small><sub>8</sub></small>(ZnMes)<small><sub>4</sub></small>]}<small><sup>3−</sup></small> (M = Nb, Ta). Structural studies are complemented by mass spectrometry and an analysis of the electronic structure using DFT. The synthesis of these clusters presents new opportunities for the construction of As-based nanomaterials.</p> |
| spellingShingle | Zhang, W-Q Morgan, HWT McGrady, JE Sun, Z-M Synthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3− (M = Nb, Ta) from binary [M@As8]3− precursors |
| title | Synthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3− (M = Nb, Ta) from binary [M@As8]3− precursors |
| title_full | Synthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3− (M = Nb, Ta) from binary [M@As8]3− precursors |
| title_fullStr | Synthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3− (M = Nb, Ta) from binary [M@As8]3− precursors |
| title_full_unstemmed | Synthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3− (M = Nb, Ta) from binary [M@As8]3− precursors |
| title_short | Synthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3− (M = Nb, Ta) from binary [M@As8]3− precursors |
| title_sort | synthesis and characterisation of the ternary intermetalloid clusters m as8 znmes 4 3 m nb ta from binary m as8 3 precursors |
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