Electrochemical glycosylation in the presence of a catalytic chemical mediator
Electrochemical glycosylation of thioglycoside donors proceeds efficiently in an undivided cell in the presence of a catalytic amount of the chemical mediator (4-bromophenyl) ammoniumyl hexachloroantimonate (BAHA). In comparison with electrochemical glycosylation alone, the use of a catalytic amount...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2008
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| _version_ | 1797092481570963456 |
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| author | Drouin, L Compton, R Fairbanks, A |
| author_facet | Drouin, L Compton, R Fairbanks, A |
| author_sort | Drouin, L |
| collection | OXFORD |
| description | Electrochemical glycosylation of thioglycoside donors proceeds efficiently in an undivided cell in the presence of a catalytic amount of the chemical mediator (4-bromophenyl) ammoniumyl hexachloroantimonate (BAHA). In comparison with electrochemical glycosylation alone, the use of a catalytic amount of BAHA greatly increases the rate of reaction, reduces the potential required and inhibits ester-protecting group migrations. Copyright © 2008 John Wiley and Sons, Ltd. |
| first_indexed | 2024-03-07T03:46:31Z |
| format | Journal article |
| id | oxford-uuid:bfa9a3a6-fdd5-4166-a26a-4baf49efa050 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:46:31Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:bfa9a3a6-fdd5-4166-a26a-4baf49efa0502022-03-27T05:49:05ZElectrochemical glycosylation in the presence of a catalytic chemical mediatorJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:bfa9a3a6-fdd5-4166-a26a-4baf49efa050EnglishSymplectic Elements at Oxford2008Drouin, LCompton, RFairbanks, AElectrochemical glycosylation of thioglycoside donors proceeds efficiently in an undivided cell in the presence of a catalytic amount of the chemical mediator (4-bromophenyl) ammoniumyl hexachloroantimonate (BAHA). In comparison with electrochemical glycosylation alone, the use of a catalytic amount of BAHA greatly increases the rate of reaction, reduces the potential required and inhibits ester-protecting group migrations. Copyright © 2008 John Wiley and Sons, Ltd. |
| spellingShingle | Drouin, L Compton, R Fairbanks, A Electrochemical glycosylation in the presence of a catalytic chemical mediator |
| title | Electrochemical glycosylation in the presence of a catalytic chemical mediator |
| title_full | Electrochemical glycosylation in the presence of a catalytic chemical mediator |
| title_fullStr | Electrochemical glycosylation in the presence of a catalytic chemical mediator |
| title_full_unstemmed | Electrochemical glycosylation in the presence of a catalytic chemical mediator |
| title_short | Electrochemical glycosylation in the presence of a catalytic chemical mediator |
| title_sort | electrochemical glycosylation in the presence of a catalytic chemical mediator |
| work_keys_str_mv | AT drouinl electrochemicalglycosylationinthepresenceofacatalyticchemicalmediator AT comptonr electrochemicalglycosylationinthepresenceofacatalyticchemicalmediator AT fairbanksa electrochemicalglycosylationinthepresenceofacatalyticchemicalmediator |