Synthesis of "phosphine tethered" η2-allene and μ-η1:η2-alkenyl complexes: Facile P-Cα bond formation and C-H activation reactions of bis(diphenylphosphino)methane with [Fe2(CO)6(μ-ER){μ-η1:η

Synthesis of "phosphine tethered" η2-allene and μ-η1:η2-alkenyl complexes: Facile P-Cα bond formation and C-H activation reactions of bis(diphenylphosphino)methane with [Fe2(CO)6(μ-ER){μ-η1:η

The phosphido-bridged diiron allenyl complex [Fe2(CO)6(μ-PPh2){μi-η 1:ηαβ2-(H)C α=Cβ=CγH2}] (1) reacts with dppm to afford, in the first instance, [Fe2(CO)6(μ-PPh2){η 1(P):η2(C)-Ph2PCH2-PPh 2(H)C=C=CH2}] (3), which contains a novel η1(P):η2(C)-dppm-functionalized allene. A single-crystal X-ray study...

Szczegółowa specyfikacja

Opis bibliograficzny
Główni autorzy:	Doherty, S, Elsegood, M, Clegg, W, Mampe, D, Rees, N
Format:	Journal article
Język:	English
Wydane:	1996

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