Synthesis of "phosphine tethered" η2-allene and μ-η1:η2-alkenyl complexes: Facile P-Cα bond formation and C-H activation reactions of bis(diphenylphosphino)methane with [Fe2(CO)6(μ-ER){μ-η1:η
The phosphido-bridged diiron allenyl complex [Fe2(CO)6(μ-PPh2){μi-η 1:ηαβ2-(H)C α=Cβ=CγH2}] (1) reacts with dppm to afford, in the first instance, [Fe2(CO)6(μ-PPh2){η 1(P):η2(C)-Ph2PCH2-PPh 2(H)C=C=CH2}] (3), which contains a novel η1(P):η2(C)-dppm-functionalized allene. A single-crystal X-ray study...
| المؤلفون الرئيسيون: | , , , , |
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| التنسيق: | Journal article |
| اللغة: | English |
| منشور في: |
1996
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