Reaction Site Diversity in the Reactions of Titanium Hydrazides with Organic Nitriles, Isonitriles and Isocyanates: Ti==N(α) Cycloaddition, Ti==N(α) Insertion and N(α)--N(β) Bond Cleavage.

Reaction Site Diversity in the Reactions of Titanium Hydrazides with Organic Nitriles, Isonitriles and Isocyanates: Ti==N(α) Cycloaddition, Ti==N(α) Insertion and N(α)--N(β) Bond Cleavage.

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We report a range of new transformations of the diamide-amine supported Ti==NNPh(2) functional group with a variety of unsaturated substrates, along with DFT studies of the key mechanisms. Reaction of [Ti(N(2)N(py))(NNPh(2))(py)] (4, N(2)N(py)=(2-NC(5)H(4))CMe(CH(2)NSiMe(3))(2); py=pyridine) with Me...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Schofield, A, Nova, A, Selby, J, Schwarz, A, Clot, E, Mountford, P
التنسيق: Journal article
اللغة:English
منشور في: 2010

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