Reaction Site Diversity in the Reactions of Titanium Hydrazides with Organic Nitriles, Isonitriles and Isocyanates: Ti==N(α) Cycloaddition, Ti==N(α) Insertion and N(α)--N(β) Bond Cleavage.
We report a range of new transformations of the diamide-amine supported Ti==NNPh(2) functional group with a variety of unsaturated substrates, along with DFT studies of the key mechanisms. Reaction of [Ti(N(2)N(py))(NNPh(2))(py)] (4, N(2)N(py)=(2-NC(5)H(4))CMe(CH(2)NSiMe(3))(2); py=pyridine) with Me...
| المؤلفون الرئيسيون: | , , , , , |
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| التنسيق: | Journal article |
| اللغة: | English |
| منشور في: |
2010
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