A diastereodivergent strategy for the asymmetric syntheses of (-)-martinellic acid and (-)-4-epi-martinellic acid

A diastereodivergent strategy for the asymmetric syntheses of (-)-martinellic acid and (-)-4-epi-martinellic acid

Asymmetric syntheses of (-)-martinellic acid and (-)-4-epi-martinellic acid were achieved in 20 steps from commercially available starting materials using a diastereodivergent strategy. The conjugate addition of lithium (R)-N-allyl-N-(α-methyl-p-methoxybenzyl)amide to tert-butyl (E)-3-[2′-(N,N-diall...

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Bibliographic Details
Main Authors:	Davies, S, Fletcher, A, Lee, J, Lorkin, T, Roberts, P, Thomson, J
Format:	Journal article
Language:	English
Published:	2013

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