Dithiane-directed Rh(III)-catalyzed amidation of unactivated C(sp3)–H bonds
An oxidant-free Rh(iii)-catalyzed direct amidation of alkyl dithianes via C(sp3)-H bond activation utilizing diverse and robust dioxazolone reagents is reported. The reaction hinges on use of a Cp*Rh(iii) complex in combination with an essential amino-carboxylate additive to generate usefully protec...
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
Royal Society of Chemistry
2019
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