Electrochemistry of Hg(II) salts in room-temperature ionic liquids.
The electrochemistry of HgCl(2) and [Hg(NTf(2))(2)] ([NTf(2)](-)=bis-{(trifluoromethyl)sulfonyl}imide) has been studied in room temperature ionic liquids. It has been found that the cyclic voltammetry of Hg(II) is strongly dependent on a number of factors (e.g., concentration, anions present in the...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2011
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| _version_ | 1797092714488004608 |
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| author | Manan, N Aldous, L Alias, Y Compton, R Lagunas, M Hardacre, C |
| author_facet | Manan, N Aldous, L Alias, Y Compton, R Lagunas, M Hardacre, C |
| author_sort | Manan, N |
| collection | OXFORD |
| description | The electrochemistry of HgCl(2) and [Hg(NTf(2))(2)] ([NTf(2)](-)=bis-{(trifluoromethyl)sulfonyl}imide) has been studied in room temperature ionic liquids. It has been found that the cyclic voltammetry of Hg(II) is strongly dependent on a number of factors (e.g., concentration, anions present in the mixture, and nature of the working electrode) and differs from that found in other media. Depending on conditions, the cyclic voltammetry of Hg(II) can give rise to one, two, or four reduction peaks, whereas the reverse oxidative scans show two to four peaks. Diffuse reflectance UV-vis spectroscopy and X-ray powder diffraction have been used to aid the assignment of the voltammetric waves. |
| first_indexed | 2024-03-07T03:49:57Z |
| format | Journal article |
| id | oxford-uuid:c0e24cf0-75d3-4705-98ba-65c55c6b426d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:49:57Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:c0e24cf0-75d3-4705-98ba-65c55c6b426d2022-03-27T05:57:33ZElectrochemistry of Hg(II) salts in room-temperature ionic liquids.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c0e24cf0-75d3-4705-98ba-65c55c6b426dEnglishSymplectic Elements at Oxford2011Manan, NAldous, LAlias, YCompton, RLagunas, MHardacre, CThe electrochemistry of HgCl(2) and [Hg(NTf(2))(2)] ([NTf(2)](-)=bis-{(trifluoromethyl)sulfonyl}imide) has been studied in room temperature ionic liquids. It has been found that the cyclic voltammetry of Hg(II) is strongly dependent on a number of factors (e.g., concentration, anions present in the mixture, and nature of the working electrode) and differs from that found in other media. Depending on conditions, the cyclic voltammetry of Hg(II) can give rise to one, two, or four reduction peaks, whereas the reverse oxidative scans show two to four peaks. Diffuse reflectance UV-vis spectroscopy and X-ray powder diffraction have been used to aid the assignment of the voltammetric waves. |
| spellingShingle | Manan, N Aldous, L Alias, Y Compton, R Lagunas, M Hardacre, C Electrochemistry of Hg(II) salts in room-temperature ionic liquids. |
| title | Electrochemistry of Hg(II) salts in room-temperature ionic liquids. |
| title_full | Electrochemistry of Hg(II) salts in room-temperature ionic liquids. |
| title_fullStr | Electrochemistry of Hg(II) salts in room-temperature ionic liquids. |
| title_full_unstemmed | Electrochemistry of Hg(II) salts in room-temperature ionic liquids. |
| title_short | Electrochemistry of Hg(II) salts in room-temperature ionic liquids. |
| title_sort | electrochemistry of hg ii salts in room temperature ionic liquids |
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