Synthesis of five-porphyrin nanorings by using ferrocene and corannulene templates
The smallest and most strained member of a family of π-conjugated cyclic porphyrin oligomers was synthesized by using pentapyridyl templates based on ferrocene and corannulene. Both templates are effective for directing the synthesis of the butadiyne-linked cyclic pentamer, despite the fact that the...
| Main Authors: | , , , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado: |
Wiley
2016
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| _version_ | 1826294797457948672 |
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| author | Liu, P Hisamune, Y Peeks, M Odell, B Gong, J Herz, L Anderson, H |
| author_facet | Liu, P Hisamune, Y Peeks, M Odell, B Gong, J Herz, L Anderson, H |
| author_sort | Liu, P |
| collection | OXFORD |
| description | The smallest and most strained member of a family of π-conjugated cyclic porphyrin oligomers was synthesized by using pentapyridyl templates based on ferrocene and corannulene. Both templates are effective for directing the synthesis of the butadiyne-linked cyclic pentamer, despite the fact that the radii of their N5 donor sets are too small by 0.5 Å and 0.9 Å, respectively (from DFT calculations). The five-porphyrin nanoring exhibits a structured absorption spectrum and its fluorescence extends to 1200 nm, reflecting strong π conjugation and Herzberg-Teller vibronic coupling. |
| first_indexed | 2024-03-07T03:51:13Z |
| format | Journal article |
| id | oxford-uuid:c151ba7c-a44a-4271-b831-fc1cd95f6d70 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:51:13Z |
| publishDate | 2016 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:c151ba7c-a44a-4271-b831-fc1cd95f6d702022-03-27T06:00:47ZSynthesis of five-porphyrin nanorings by using ferrocene and corannulene templatesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c151ba7c-a44a-4271-b831-fc1cd95f6d70EnglishSymplectic Elements at OxfordWiley2016Liu, PHisamune, YPeeks, MOdell, BGong, JHerz, LAnderson, HThe smallest and most strained member of a family of π-conjugated cyclic porphyrin oligomers was synthesized by using pentapyridyl templates based on ferrocene and corannulene. Both templates are effective for directing the synthesis of the butadiyne-linked cyclic pentamer, despite the fact that the radii of their N5 donor sets are too small by 0.5 Å and 0.9 Å, respectively (from DFT calculations). The five-porphyrin nanoring exhibits a structured absorption spectrum and its fluorescence extends to 1200 nm, reflecting strong π conjugation and Herzberg-Teller vibronic coupling. |
| spellingShingle | Liu, P Hisamune, Y Peeks, M Odell, B Gong, J Herz, L Anderson, H Synthesis of five-porphyrin nanorings by using ferrocene and corannulene templates |
| title | Synthesis of five-porphyrin nanorings by using ferrocene and corannulene templates |
| title_full | Synthesis of five-porphyrin nanorings by using ferrocene and corannulene templates |
| title_fullStr | Synthesis of five-porphyrin nanorings by using ferrocene and corannulene templates |
| title_full_unstemmed | Synthesis of five-porphyrin nanorings by using ferrocene and corannulene templates |
| title_short | Synthesis of five-porphyrin nanorings by using ferrocene and corannulene templates |
| title_sort | synthesis of five porphyrin nanorings by using ferrocene and corannulene templates |
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