ASYMMETRIC-SYNTHESIS OF THE ENANTIOMERS OF THE DIARYLCARBINOL (1R)-1-(1-HYDROXYPHENYLMETHYL)-2-HYDROXYBENZENE AND (1S)-1-(1-HYDROXYPHENYLMETHYL)-2-HYDROXYBENZENE
(1S)-1-Phenethyl(phenyl chromium tricarbonyl) ether (-)-4 undergoes completely stereoselective ortho-deprotonation with the thus formed carbanion being converted by the complementary sequences, benzoylation/hydride reduction and formylation/PhMgBr addition, to generate after decomplexation and depro...
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Bibliographic Details
| Main Authors: |
Davies, S,
Hume, W |
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| Format: | Journal article
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| Language: | English |
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| Published: |
1995
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