ASYMMETRIC-SYNTHESIS OF THE ENANTIOMERS OF THE DIARYLCARBINOL (1R)-1-(1-HYDROXYPHENYLMETHYL)-2-HYDROXYBENZENE AND (1S)-1-(1-HYDROXYPHENYLMETHYL)-2-HYDROXYBENZENE
(1S)-1-Phenethyl(phenyl chromium tricarbonyl) ether (-)-4 undergoes completely stereoselective ortho-deprotonation with the thus formed carbanion being converted by the complementary sequences, benzoylation/hydride reduction and formylation/PhMgBr addition, to generate after decomplexation and depro...
Hoofdauteurs: | Davies, S, Hume, W |
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Formaat: | Journal article |
Taal: | English |
Gepubliceerd in: |
1995
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