Investigating the diameter-dependent stability of single-walled carbon nanotubes

We investigate the long-standing question of whether electrons accelerated at 80 kV are below the knock-on damage threshold for single-walled carbon nanotubes (SWNTs). Aberration-corrected high-resolution transmission electron microscopy is used to directly image the atomic structure of the SWNTs an...

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Egile Nagusiak: Warner, J, Schäffel, F, Zhong, G, Rümmeli, M, Büchner, B, Robertson, J, Briggs, G
Formatua: Journal article
Hizkuntza:English
Argitaratua: 2009
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author Warner, J
Schäffel, F
Zhong, G
Rümmeli, M
Büchner, B
Robertson, J
Briggs, G
author_facet Warner, J
Schäffel, F
Zhong, G
Rümmeli, M
Büchner, B
Robertson, J
Briggs, G
author_sort Warner, J
collection OXFORD
description We investigate the long-standing question of whether electrons accelerated at 80 kV are below the knock-on damage threshold for single-walled carbon nanotubes (SWNTs). Aberration-corrected high-resolution transmission electron microscopy is used to directly image the atomic structure of the SWNTs and provides in situ monitoring of the structural modification induced by electron beam irradiation at 80 kV. We find that SWNTs with small diameters of 1 nm are damaged by the electron beam, and defects are produced in the side walls that can lead to their destruction. SWNTs with diameters of 1.3 nm and larger are more stable against degradation, and stability increases with diameter. The effect of diameter, defects, and exterior contamination on the inherent stability of SWNTs under electron beam irradiation is investigated. © 2009 American Chemical Society.
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spelling oxford-uuid:c2ba8602-3dd3-4c8e-9103-103c9e2c53b52022-03-27T06:10:59ZInvestigating the diameter-dependent stability of single-walled carbon nanotubesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c2ba8602-3dd3-4c8e-9103-103c9e2c53b5EnglishSymplectic Elements at Oxford2009Warner, JSchäffel, FZhong, GRümmeli, MBüchner, BRobertson, JBriggs, GWe investigate the long-standing question of whether electrons accelerated at 80 kV are below the knock-on damage threshold for single-walled carbon nanotubes (SWNTs). Aberration-corrected high-resolution transmission electron microscopy is used to directly image the atomic structure of the SWNTs and provides in situ monitoring of the structural modification induced by electron beam irradiation at 80 kV. We find that SWNTs with small diameters of 1 nm are damaged by the electron beam, and defects are produced in the side walls that can lead to their destruction. SWNTs with diameters of 1.3 nm and larger are more stable against degradation, and stability increases with diameter. The effect of diameter, defects, and exterior contamination on the inherent stability of SWNTs under electron beam irradiation is investigated. © 2009 American Chemical Society.
spellingShingle Warner, J
Schäffel, F
Zhong, G
Rümmeli, M
Büchner, B
Robertson, J
Briggs, G
Investigating the diameter-dependent stability of single-walled carbon nanotubes
title Investigating the diameter-dependent stability of single-walled carbon nanotubes
title_full Investigating the diameter-dependent stability of single-walled carbon nanotubes
title_fullStr Investigating the diameter-dependent stability of single-walled carbon nanotubes
title_full_unstemmed Investigating the diameter-dependent stability of single-walled carbon nanotubes
title_short Investigating the diameter-dependent stability of single-walled carbon nanotubes
title_sort investigating the diameter dependent stability of single walled carbon nanotubes
work_keys_str_mv AT warnerj investigatingthediameterdependentstabilityofsinglewalledcarbonnanotubes
AT schaffelf investigatingthediameterdependentstabilityofsinglewalledcarbonnanotubes
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AT rummelim investigatingthediameterdependentstabilityofsinglewalledcarbonnanotubes
AT buchnerb investigatingthediameterdependentstabilityofsinglewalledcarbonnanotubes
AT robertsonj investigatingthediameterdependentstabilityofsinglewalledcarbonnanotubes
AT briggsg investigatingthediameterdependentstabilityofsinglewalledcarbonnanotubes