Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

There are relatively few metal-organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of...

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Main Authors: Smalley, AP, Reid, DG, Tan, J-C, Lloyd, GO
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2013
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author Smalley, AP
Reid, DG
Tan, J-C
Lloyd, GO
author_facet Smalley, AP
Reid, DG
Tan, J-C
Lloyd, GO
author_sort Smalley, AP
collection OXFORD
description There are relatively few metal-organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.
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spelling oxford-uuid:c3659522-3448-40f6-b6af-956723ab84fe2025-02-18T10:06:49ZAlternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c3659522-3448-40f6-b6af-956723ab84feEnglishSymplectic Elements at OxfordRoyal Society of Chemistry2013Smalley, APReid, DGTan, J-CLloyd, GOThere are relatively few metal-organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.
spellingShingle Smalley, AP
Reid, DG
Tan, J-C
Lloyd, GO
Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2
title Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2
title_full Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2
title_fullStr Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2
title_full_unstemmed Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2
title_short Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2
title_sort alternative synthetic methodology for amide formation in the post synthetic modification of ti mil125 nh2
work_keys_str_mv AT smalleyap alternativesyntheticmethodologyforamideformationinthepostsyntheticmodificationoftimil125nh2
AT reiddg alternativesyntheticmethodologyforamideformationinthepostsyntheticmodificationoftimil125nh2
AT tanjc alternativesyntheticmethodologyforamideformationinthepostsyntheticmodificationoftimil125nh2
AT lloydgo alternativesyntheticmethodologyforamideformationinthepostsyntheticmodificationoftimil125nh2