Synthesis of cyclic alkenyl dimethylsiloxanes from alkynyl benzyldimethylsilanes and application in polyene synthesis
Cyclic dimethylalkenylsiloxanes, useful motifs for (Z)-selective Hiyama cross-coupling, are accessed from alkynyl benzyldimethylsilanes featuring adjacent allylic or homoallylic oxygen substituents by semihydrogenation/debenzylation/cyclization. While formation of 5- and 6-membered rings can be achi...
Celý popis
Podrobná bibliografie
| Hlavní autoři: |
Gudmundsson, HG,
Kuper, CJ,
Cornut, D,
Urbitsch, F,
Elbert, BL,
Anderson, EA |
|---|
| Médium: | Journal article
|
|---|
| Jazyk: | English |
|---|
| Vydáno: |
American Chemical Society
2019
|
|---|