Synthesis of cyclic alkenyl dimethylsiloxanes from alkynyl benzyldimethylsilanes and application in polyene synthesis
Cyclic dimethylalkenylsiloxanes, useful motifs for (Z)-selective Hiyama cross-coupling, are accessed from alkynyl benzyldimethylsilanes featuring adjacent allylic or homoallylic oxygen substituents by semihydrogenation/debenzylation/cyclization. While formation of 5- and 6-membered rings can be achi...
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Bibliographic Details
| Main Authors: |
Gudmundsson, HG,
Kuper, CJ,
Cornut, D,
Urbitsch, F,
Elbert, BL,
Anderson, EA |
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| Format: | Journal article
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| Language: | English |
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| Published: |
American Chemical Society
2019
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