A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state
The straightforward synthesis of two cationic iridium norbornadiene species bearing simple bidentate phosphines is reported [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] [NBD = norbornadiene; R = tBu, Cy; ArF = 3,5-C6H3(CF3)2]. The hydrogenation of [Ir(tBu2PCH2CH2PtBu2)(NBD)][BAr4F] in the solution phase and in th...
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| Format: | Journal article |
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Elsevier
2015
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| _version_ | 1797093450821140480 |
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| author | Chadwick, F Olliff, N Weller, A |
| author_facet | Chadwick, F Olliff, N Weller, A |
| author_sort | Chadwick, F |
| collection | OXFORD |
| description | The straightforward synthesis of two cationic iridium norbornadiene species bearing simple bidentate phosphines is reported [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] [NBD = norbornadiene; R = tBu, Cy; ArF = 3,5-C6H3(CF3)2]. The hydrogenation of [Ir(tBu2PCH2CH2PtBu2)(NBD)][BAr4F] in the solution phase and in the solid state is described in which saturated (solution) or unsaturated (solid-state) dimeric species with bridging hydrides are formed. The solid-state structures, as determined by single crystal X-ray diffraction, of these dimeric species are also discussed. |
| first_indexed | 2024-03-07T04:00:35Z |
| format | Journal article |
| id | oxford-uuid:c470aea1-552c-426b-9b97-c4a69355d715 |
| institution | University of Oxford |
| last_indexed | 2024-03-07T04:00:35Z |
| publishDate | 2015 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | oxford-uuid:c470aea1-552c-426b-9b97-c4a69355d7152022-03-27T06:23:31ZA convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-stateJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c470aea1-552c-426b-9b97-c4a69355d715Symplectic Elements at OxfordElsevier2015Chadwick, FOlliff, NWeller, AThe straightforward synthesis of two cationic iridium norbornadiene species bearing simple bidentate phosphines is reported [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] [NBD = norbornadiene; R = tBu, Cy; ArF = 3,5-C6H3(CF3)2]. The hydrogenation of [Ir(tBu2PCH2CH2PtBu2)(NBD)][BAr4F] in the solution phase and in the solid state is described in which saturated (solution) or unsaturated (solid-state) dimeric species with bridging hydrides are formed. The solid-state structures, as determined by single crystal X-ray diffraction, of these dimeric species are also discussed. |
| spellingShingle | Chadwick, F Olliff, N Weller, A A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state |
| title | A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state |
| title_full | A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state |
| title_fullStr | A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state |
| title_full_unstemmed | A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state |
| title_short | A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state |
| title_sort | convenient route to a norbornadiene adduct of iridium with chelating phosphines ir r2pch2ch2pr2 nbd bar4f and a comparison of reactivity with h2 in solution and the solid state |
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