A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state

A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state

The straightforward synthesis of two cationic iridium norbornadiene species bearing simple bidentate phosphines is reported [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] [NBD = norbornadiene; R = tBu, Cy; ArF = 3,5-C6H3(CF3)2]. The hydrogenation of [Ir(tBu2PCH2CH2PtBu2)(NBD)][BAr4F] in the solution phase and in th...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون:	Chadwick, F, Olliff, N, Weller, A
التنسيق:	Journal article
منشور في:	Elsevier 2015

مواد مشابهة

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منشور في: (2004)

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HYDRIDE REDUCTION OF THE CATION [ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
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HYDRIDE REDUCTION OF THE CATION [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
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منشور في: (2014)

REGIOSELECTIVITY OF HYDRIDE ADDITION TO [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 AND REARRANGEMENT OF "(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)(CO)H TO (ETA-4-C5H6)FE(PH2PCH2CH2PPH2)CO
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Exploring (Ph2PCH2CH2)2E Ligand Space (E = O, S, PPh) in RhI Alkene Complexes as Potential Hydroacylation Catalysts
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DISPROPORTIONATION OF THE IRON CARBONYL HYDRIDE "(ETA-5-C5H5)FE(CO)H(PH2PCH2CH2PPH2) TO THE IRON METHYL (ETA-5-C5H5)FE(PH2PCH2CH2PPH2)ME
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منشور في: (1982)

CARBON-MONOXIDE REDUCTION - [FE(ETA-5-C5H5)(PH2PCH2CH2PPH2)(CO)H] - REACTIONS AND FORMATION BY REDUCTION OF THE COMPLEX [FE(ETA-5-C5H5)(PH2PCH2CH2PPH2)(CO)]PF6
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منشور في: (1984)

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منشور في: (2016)

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SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ELECTRON RICH COMPLEXES CO(ETA-C5ME5)(R2PCH2CH2PR2)(R=ME,PH) - PHOTOELECTRON SPECTROSCOPIC STUDIES OF SOME PENTAMETHYLCYCLOPENTADIENYLPHOSPHINECOBALT COMPLEXES
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pCH1497-ASD1
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منشور في: (1980)

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منشور في: (2005)

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منشور في: (1981)

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منشور في: (2015)

Crystal and molecular structures of two 1:1 adducts of bis(O-ethyl dithiocarbonato-S,S `)manganese(II): Mn(S2COCH2CH3)(2) (1,10-phenanthroline) and Mn(S2COCH2CH3)(2) (2,2 `-bipyridyl)
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منشور في: (2010)

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منشور في: (2005)

SUBSTITUTION-REACTIONS OF THE ZEROVALENT IRON COMPLEXES [FE(ETA-C6H6)(PME3)2] AND [FE(ETA-C6H6)(ME2PCH2CH2PME2)]
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منشور في: (2004)

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منشور في: (2013)

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حسب: Moxham, G, وآخرون
منشور في: (2006)

Selected ion flow tube study of the reactions of O- and O-2(-) with CHCl2F, CHClF2, CHF3, CH2ClF, CH2F2 CH3F, CHF2CHF2, CH2FCF3, and CH3CHF2
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Magnetisation reversal in Ca2PrCr2NbO9 and Ca2PrCr2TaO9
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منشور في: (2018)

HYDRIDE REDUCTION OF THE CATION [(ETA-5-C5H5)FE(TRIPHOS)]PF6 - DIRECT NUCLEOPHILIC-ATTACK ON THE METAL, AND HYDROGEN-EXCHANGE IN THE PRODUCT HYDRIDE (ETA-5-C5H5)FEH(TRIPHOS), (TRIPHOS=PH2PCH2CH2PPHCH2CH2PPH2)
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