A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state

A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state

The straightforward synthesis of two cationic iridium norbornadiene species bearing simple bidentate phosphines is reported [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] [NBD = norbornadiene; R = tBu, Cy; ArF = 3,5-C6H3(CF3)2]. The hydrogenation of [Ir(tBu2PCH2CH2PtBu2)(NBD)][BAr4F] in the solution phase and in th...

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Manylion Llyfryddiaeth
Prif Awduron:	Chadwick, F, Olliff, N, Weller, A
Fformat:	Journal article
Cyhoeddwyd:	Elsevier 2015

Eitemau Tebyg

Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P.BH3.
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Cyhoeddwyd: (2004)

Chelating monoborane phosphines: Rational and high-yield synthesis of [(COD)Rh{(eta(2)-BH(3))Ph(2)PCH(2)PPh(2)}][PF(6)] (COD=1,5-cyclooctadiene)
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Cyhoeddwyd: (2001)

HYDRIDE REDUCTION OF THE CATION [ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
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Cyhoeddwyd: (1982)

HYDRIDE REDUCTION OF THE CATION [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
gan: Davies, S, et al.
Cyhoeddwyd: (1983)

REGIOSELECTIVITY OF HYDRIDE ADDITION TO [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 AND REARRANGEMENT OF "(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)(CO)H TO (ETA-4-C5H6)FE(PH2PCH2CH2PPH2)CO
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Cyhoeddwyd: (1983)

Solid-state synthesis and characterization of σ-alkane complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine)
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Cyhoeddwyd: (2014)

Exploring (Ph2PCH2CH2)2E Ligand Space (E = O, S, PPh) in RhI Alkene Complexes as Potential Hydroacylation Catalysts
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Cyhoeddwyd: (2011)

Mononuclear and dinuclear complexes with a [Ru(tBu2PCH2CH2PtBu2)(CO)] core.
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Cyhoeddwyd: (2005)

DISPROPORTIONATION OF THE IRON CARBONYL HYDRIDE "(ETA-5-C5H5)FE(CO)H(PH2PCH2CH2PPH2) TO THE IRON METHYL (ETA-5-C5H5)FE(PH2PCH2CH2PPH2)ME
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Evidence for a SN2-type pathway for phosphine exchange in phosphine-phosphenium cations, [R2P--PR'3]+.
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Ruthenium(II) complexes of the chelating phosphine borane H2ClB center dot dppm
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Cyhoeddwyd: (2005)

EVIDENCE FOR THE IRON FORMYL "(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)(CHO)
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Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines
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Cyhoeddwyd: (2010)

Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines
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Cyhoeddwyd: (2010)

CARBON-MONOXIDE REDUCTION - [FE(ETA-5-C5H5)(PH2PCH2CH2PPH2)(CO)H] - REACTIONS AND FORMATION BY REDUCTION OF THE COMPLEX [FE(ETA-5-C5H5)(PH2PCH2CH2PPH2)(CO)]PF6
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Cyhoeddwyd: (1984)

REACTIVITY OF THE INORGANO-GRIGNARD "(ETA-5-C5H5)(PH2PCH2CH2PPH2)-FEMGBR TOWARDS HALOGENOGERMANES
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Cyhoeddwyd: (1981)

Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]
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Cyhoeddwyd: (2016)

Mutations in the linker domain of NBD2 of SUR inhibit transduction but not nucleotide binding.
gan: Matsuo, M, et al.
Cyhoeddwyd: (2002)

SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ELECTRON RICH COMPLEXES CO(ETA-C5ME5)(R2PCH2CH2PR2)(R=ME,PH) - PHOTOELECTRON SPECTROSCOPIC STUDIES OF SOME PENTAMETHYLCYCLOPENTADIENYLPHOSPHINECOBALT COMPLEXES
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Cyhoeddwyd: (1983)

Synthesis and crystal structures of [Ph3PCH2PPh3]I2 dichloromethane disolvate and [Ph3PCH2PPh3](BI4)2
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Cyhoeddwyd: (2017)

TERTIARY PHOSPHINE ADDUCTS OF [W2(MU-O2CBU(T))4] - CRYSTAL-STRUCTURE OF [W2(MU-O2CBU(T))3(O2CBU(T)) (PME2PH)2]
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pCH1497-ASD1
gan: Canton, Bartholomew
Cyhoeddwyd: (2008)

CHEMISTRY OF (ETA-5-C5H5)RU(PH2PCH2CH2PPH2)CL - PREPARATION OF CATIONIC RUTHENIUM OLEFIN COMPLEXES
gan: Davies, S, et al.
Cyhoeddwyd: (1980)

HYDRIDE ADDITION TO THE CATIONS [( ETA-5-C5H5)RU(L)2CO]+ (L=PPH3, L2=PH2PCH2CH2PPH2)
gan: Davies, S, et al.
Cyhoeddwyd: (1984)

Dihydrogen complexes of rhodium: [RhH2(H2)x (PR3)2]+ (R = Cy, iPr; x = 1, 2).
gan: Ingleson, M, et al.
Cyhoeddwyd: (2005)

HYDRIDE REDUCTION OF THE CATIONS "((ETA-5-C5H5)FE[(PH2PCH2)3CME])PF6, ((ETA-5-C5H5)-RU[(PH2PCH2CH2)2PPH])PF6, AND ((ETA-5-C5H5)RU[PH2PCH2)3CME])PF6 - REGIOSELECTIVITY AND MECHANISM
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Cyhoeddwyd: (1981)

Synthesis and characterisation of the aminocarbene complexes [(eta(5)-C5H5)Fe(CO)(PPh3){=C(NHR2)(CH2R1)}]+BF4- [R-1 = H, Me or Pr; R-2 = H, Me, Et, CHMe2, CH2Ph, CH(Me)Ph, CH2CH=CH2 or CH2CH2OH]
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Cyhoeddwyd: (1998)

Dehydrocoupling of phosphine-boranes using the [RhCp∗Me(PMe3)(CH2Cl2)][BArF 4] precatalyst: Stoichiometric and catalytic studies
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Cyhoeddwyd: (2015)

Crystal and molecular structures of two 1:1 adducts of bis(O-ethyl dithiocarbonato-S,S `)manganese(II): Mn(S2COCH2CH3)(2) (1,10-phenanthroline) and Mn(S2COCH2CH3)(2) (2,2 `-bipyridyl)
gan: Campian, M.V., et al.
Cyhoeddwyd: (2010)

The 2-phosphaethynolate anion: a convenient synthesis and [2+2] cycloaddition chemistry.
gan: Jupp, A, et al.
Cyhoeddwyd: (2013)

New group 10 complexes of the bulky iminophosphine ligands [Ph2PCH2C(Ph)=N(2,6-R2C6H3)], where R = Me, Pr-i
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Cyhoeddwyd: (2005)

SUBSTITUTION-REACTIONS OF THE ZEROVALENT IRON COMPLEXES [FE(ETA-C6H6)(PME3)2] AND [FE(ETA-C6H6)(ME2PCH2CH2PME2)]
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Cyhoeddwyd: (1989)

[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex.
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Cyhoeddwyd: (2007)

The reaction of M(CO)3(Ph2PCH2CH2PPh2)(M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products.
gan: Schott, D, et al.
Cyhoeddwyd: (2004)

Selected ion flow tube study of the reactions of O- and O-2(-) with CHCl2F, CHClF2, CHF3, CH2ClF, CH2F2 CH3F, CHF2CHF2, CH2FCF3, and CH3CHF2
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Cyhoeddwyd: (1997)

The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.
gan: Moxham, G, et al.
Cyhoeddwyd: (2006)

Revealing the P-B coupling event in the rhodium catalysed dehydrocoupling of phosphine-boranes H3B center dot PR2H (R = Bu-t, Ph)
gan: Huertos, M, et al.
Cyhoeddwyd: (2013)

Magnetisation reversal in Ca2PrCr2NbO9 and Ca2PrCr2TaO9
gan: Hunter, E, et al.
Cyhoeddwyd: (2018)

HYDRIDE REDUCTION OF THE CATION [(ETA-5-C5H5)FE(TRIPHOS)]PF6 - DIRECT NUCLEOPHILIC-ATTACK ON THE METAL, AND HYDROGEN-EXCHANGE IN THE PRODUCT HYDRIDE (ETA-5-C5H5)FEH(TRIPHOS), (TRIPHOS=PH2PCH2CH2PPHCH2CH2PPH2)
gan: Davies, S, et al.
Cyhoeddwyd: (1980)

On the nature of the bonding in 1:1 adducts of O2.
gan: Pantazis, D, et al.
Cyhoeddwyd: (2003)