Heteronuclear bipyrimidine-bridged Ru-Ln and Os-Ln dyads: low-energy 3MLCT states as energy-donors to Yb(III) and Nd(III).

Heteronuclear bipyrimidine-bridged Ru-Ln and Os-Ln dyads: low-energy 3MLCT states as energy-donors to Yb(III) and Nd(III).

The complexes [Ru((t)Bu(2)bipy)(bpym)X(2)] (X = Cl, NCS) and [M((t)Bu(2)bipy)(2)(bpym)][PF(6)](2) (M = Ru, Os) all have a low-energy LUMO arising from the presence of a 2,2'-bipyrimidine ligand, and consequently have lower-energy (1)MLCT and (3)MLCT states than analogous complexes of bipyridine...

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Detalles Bibliográficos
Autores principales: Lazarides, T, Adams, H, Sykes, D, Faulkner, S, Calogero, G, Ward, MD
Formato: Journal article
Lenguaje:English
Publicado: 2008

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