Selective deintercalation of apex over face-shared oxide ions in the topotactic reduction of Sr7Mn4O15 to Sr7Mn4O12.

Sodium hydride selectively deintercalates the apex rather than face-shared oxide ions within the structure of Sr(7)Mn(4)O(15) leading to the formation of the structurally related reduced phase Sr(7)Mn(4)O(12).

Sonraí bibleagrafaíochta
Príomhchruthaitheoir: Hayward, M
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 2004