RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS

The synthesis of 10-15 membered α-methylene lactones 1 from the functionalised allyl stannanes 2 occurs cleanly in moderate to high yield under free radical conditions via an intramolecular SH2′ reaction.

Bibliographic Details
Main Authors: Baldwin, J, Adlington, R, Mitchell, M, Robertson, J
Format: Journal article
Language:English
Published: 1990
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author Baldwin, J
Adlington, R
Mitchell, M
Robertson, J
author_facet Baldwin, J
Adlington, R
Mitchell, M
Robertson, J
author_sort Baldwin, J
collection OXFORD
description The synthesis of 10-15 membered α-methylene lactones 1 from the functionalised allyl stannanes 2 occurs cleanly in moderate to high yield under free radical conditions via an intramolecular SH2′ reaction.
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publishDate 1990
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spelling oxford-uuid:c61ab5b7-345a-4d1d-9ca6-d42c6d1377b92022-03-27T06:35:46ZRADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c61ab5b7-345a-4d1d-9ca6-d42c6d1377b9EnglishSymplectic Elements at Oxford1990Baldwin, JAdlington, RMitchell, MRobertson, JThe synthesis of 10-15 membered α-methylene lactones 1 from the functionalised allyl stannanes 2 occurs cleanly in moderate to high yield under free radical conditions via an intramolecular SH2′ reaction.
spellingShingle Baldwin, J
Adlington, R
Mitchell, M
Robertson, J
RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS
title RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS
title_full RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS
title_fullStr RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS
title_full_unstemmed RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS
title_short RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS
title_sort radical reactions in synthesis intramolecular sh2 macrocyclisations
work_keys_str_mv AT baldwinj radicalreactionsinsynthesisintramolecularsh2macrocyclisations
AT adlingtonr radicalreactionsinsynthesisintramolecularsh2macrocyclisations
AT mitchellm radicalreactionsinsynthesisintramolecularsh2macrocyclisations
AT robertsonj radicalreactionsinsynthesisintramolecularsh2macrocyclisations