RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS
The synthesis of 10-15 membered α-methylene lactones 1 from the functionalised allyl stannanes 2 occurs cleanly in moderate to high yield under free radical conditions via an intramolecular SH2′ reaction.
Main Authors: | , , , |
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Format: | Journal article |
Language: | English |
Published: |
1990
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_version_ | 1826295746057469952 |
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author | Baldwin, J Adlington, R Mitchell, M Robertson, J |
author_facet | Baldwin, J Adlington, R Mitchell, M Robertson, J |
author_sort | Baldwin, J |
collection | OXFORD |
description | The synthesis of 10-15 membered α-methylene lactones 1 from the functionalised allyl stannanes 2 occurs cleanly in moderate to high yield under free radical conditions via an intramolecular SH2′ reaction. |
first_indexed | 2024-03-07T04:05:47Z |
format | Journal article |
id | oxford-uuid:c61ab5b7-345a-4d1d-9ca6-d42c6d1377b9 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T04:05:47Z |
publishDate | 1990 |
record_format | dspace |
spelling | oxford-uuid:c61ab5b7-345a-4d1d-9ca6-d42c6d1377b92022-03-27T06:35:46ZRADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c61ab5b7-345a-4d1d-9ca6-d42c6d1377b9EnglishSymplectic Elements at Oxford1990Baldwin, JAdlington, RMitchell, MRobertson, JThe synthesis of 10-15 membered α-methylene lactones 1 from the functionalised allyl stannanes 2 occurs cleanly in moderate to high yield under free radical conditions via an intramolecular SH2′ reaction. |
spellingShingle | Baldwin, J Adlington, R Mitchell, M Robertson, J RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS |
title | RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS |
title_full | RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS |
title_fullStr | RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS |
title_full_unstemmed | RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS |
title_short | RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS |
title_sort | radical reactions in synthesis intramolecular sh2 macrocyclisations |
work_keys_str_mv | AT baldwinj radicalreactionsinsynthesisintramolecularsh2macrocyclisations AT adlingtonr radicalreactionsinsynthesisintramolecularsh2macrocyclisations AT mitchellm radicalreactionsinsynthesisintramolecularsh2macrocyclisations AT robertsonj radicalreactionsinsynthesisintramolecularsh2macrocyclisations |