A new class of alumina-forming superalloy for 3D printing

A new class of crack-resistant nickel-based superalloy containing high 𝛾′ fraction is studied for the laser-powder bed fusion (L-PBF) process. The effects of the (Nb+Ta)/Al ratio is emphasized, a strategy that is shown to confer excellent low-temperature strength whilst maintaining oxidation resista...

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Main Authors: Ghoussoub, JN, Klupś, P, Dick-Cleland, WJB, Rankin, KE, Utada, S, Bagot, PAJ, McCartney, DG, Tang, YT, Reed, RC
פורמט: Journal article
שפה:English
יצא לאור: Elsevier 2022
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author Ghoussoub, JN
Klupś, P
Dick-Cleland, WJB
Rankin, KE
Utada, S
Bagot, PAJ
McCartney, DG
Tang, YT
Reed, RC
author_facet Ghoussoub, JN
Klupś, P
Dick-Cleland, WJB
Rankin, KE
Utada, S
Bagot, PAJ
McCartney, DG
Tang, YT
Reed, RC
author_sort Ghoussoub, JN
collection OXFORD
description A new class of crack-resistant nickel-based superalloy containing high 𝛾′ fraction is studied for the laser-powder bed fusion (L-PBF) process. The effects of the (Nb+Ta)/Al ratio is emphasized, a strategy that is shown to confer excellent low-temperature strength whilst maintaining oxidation resistance at high temperatures via stable alumina scale formation. The processability of the new alloys is characterized with respect to defect assessment by micro-focus X-ray computed tomography; use is made of a prototype turbine blade geometry and the heritage alloy CM247LC as a benchmark. In all cases, some processing-related porosity is present in thin wall sections such as the trailing edge, but this can be avoided by judicious processing. The cracking seen in CM247LC – in solid-state, liquation and solidification forms – is avoided. A novel sub-solvus heat treatment strategy is proposed which takes advantage of AM not requiring solutioning; super-solvus heat treatment is inappropriate since it embrittles the material by deterioration of the texture and coarsening of grain boundary carbides. The tensile strength of the new superalloy is greatest when the Nb+Ta content is highest and exceeds that of CM247LC up to ∼900 ◦C. The oxidation resistance is best when Al content is highest, and oxidation-assisted cracking resistance maximized when the (Nb+Ta)/Al ratio is balanced. In all cases these are equivalent or superior to that of CM247LC. Nevertheless, the creep resistance of the new alloys is somewhat inferior to that of CM247LC for which the 𝛾′, C, and B contents are higher; this implies a processing/property trade-off which requires further clarification.
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spelling oxford-uuid:c6d108fb-18bb-446b-8e9e-90b50b464f7e2022-03-27T06:40:37ZA new class of alumina-forming superalloy for 3D printingJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c6d108fb-18bb-446b-8e9e-90b50b464f7eEnglishSymplectic ElementsElsevier2022Ghoussoub, JNKlupś, PDick-Cleland, WJBRankin, KEUtada, SBagot, PAJMcCartney, DGTang, YTReed, RCA new class of crack-resistant nickel-based superalloy containing high 𝛾′ fraction is studied for the laser-powder bed fusion (L-PBF) process. The effects of the (Nb+Ta)/Al ratio is emphasized, a strategy that is shown to confer excellent low-temperature strength whilst maintaining oxidation resistance at high temperatures via stable alumina scale formation. The processability of the new alloys is characterized with respect to defect assessment by micro-focus X-ray computed tomography; use is made of a prototype turbine blade geometry and the heritage alloy CM247LC as a benchmark. In all cases, some processing-related porosity is present in thin wall sections such as the trailing edge, but this can be avoided by judicious processing. The cracking seen in CM247LC – in solid-state, liquation and solidification forms – is avoided. A novel sub-solvus heat treatment strategy is proposed which takes advantage of AM not requiring solutioning; super-solvus heat treatment is inappropriate since it embrittles the material by deterioration of the texture and coarsening of grain boundary carbides. The tensile strength of the new superalloy is greatest when the Nb+Ta content is highest and exceeds that of CM247LC up to ∼900 ◦C. The oxidation resistance is best when Al content is highest, and oxidation-assisted cracking resistance maximized when the (Nb+Ta)/Al ratio is balanced. In all cases these are equivalent or superior to that of CM247LC. Nevertheless, the creep resistance of the new alloys is somewhat inferior to that of CM247LC for which the 𝛾′, C, and B contents are higher; this implies a processing/property trade-off which requires further clarification.
spellingShingle Ghoussoub, JN
Klupś, P
Dick-Cleland, WJB
Rankin, KE
Utada, S
Bagot, PAJ
McCartney, DG
Tang, YT
Reed, RC
A new class of alumina-forming superalloy for 3D printing
title A new class of alumina-forming superalloy for 3D printing
title_full A new class of alumina-forming superalloy for 3D printing
title_fullStr A new class of alumina-forming superalloy for 3D printing
title_full_unstemmed A new class of alumina-forming superalloy for 3D printing
title_short A new class of alumina-forming superalloy for 3D printing
title_sort new class of alumina forming superalloy for 3d printing
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