Self-assembled xanthate-transition metal polyether macrocycles and cryptands
The synthesis of novel dinuclear nickel(II)-xanthate polyether macrocycles and dinuclear cobalt(III)-xanthate polyether cryptands is reported. The assemblies have been characterised by a range of spectroscopic techniques and in one case by X-ray crystal structure determination. Electrospray mass spe...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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2003
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| _version_ | 1797093994970218496 |
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| author | Beer, P Cowley, A Jeffery, J Paul, R Wong, W |
| author_facet | Beer, P Cowley, A Jeffery, J Paul, R Wong, W |
| author_sort | Beer, P |
| collection | OXFORD |
| description | The synthesis of novel dinuclear nickel(II)-xanthate polyether macrocycles and dinuclear cobalt(III)-xanthate polyether cryptands is reported. The assemblies have been characterised by a range of spectroscopic techniques and in one case by X-ray crystal structure determination. Electrospray mass spectrometry provided evidence that the dinuclear nickel(II)-xanthate macrocycles form adducts with Group I metal cations and methyl viologen (MV2+). The dinuclear cobalt(III)-xanthate cryptands also form adducts with Group I metal cations but did not interact with MV2+. © 2003 Elsevier Science Ltd. All rights reserved. |
| first_indexed | 2024-03-07T04:08:03Z |
| format | Journal article |
| id | oxford-uuid:c6e29592-32b9-43e4-b99b-a25130d82abd |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:08:03Z |
| publishDate | 2003 |
| record_format | dspace |
| spelling | oxford-uuid:c6e29592-32b9-43e4-b99b-a25130d82abd2022-03-27T06:41:06ZSelf-assembled xanthate-transition metal polyether macrocycles and cryptandsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c6e29592-32b9-43e4-b99b-a25130d82abdEnglishSymplectic Elements at Oxford2003Beer, PCowley, AJeffery, JPaul, RWong, WThe synthesis of novel dinuclear nickel(II)-xanthate polyether macrocycles and dinuclear cobalt(III)-xanthate polyether cryptands is reported. The assemblies have been characterised by a range of spectroscopic techniques and in one case by X-ray crystal structure determination. Electrospray mass spectrometry provided evidence that the dinuclear nickel(II)-xanthate macrocycles form adducts with Group I metal cations and methyl viologen (MV2+). The dinuclear cobalt(III)-xanthate cryptands also form adducts with Group I metal cations but did not interact with MV2+. © 2003 Elsevier Science Ltd. All rights reserved. |
| spellingShingle | Beer, P Cowley, A Jeffery, J Paul, R Wong, W Self-assembled xanthate-transition metal polyether macrocycles and cryptands |
| title | Self-assembled xanthate-transition metal polyether macrocycles and cryptands |
| title_full | Self-assembled xanthate-transition metal polyether macrocycles and cryptands |
| title_fullStr | Self-assembled xanthate-transition metal polyether macrocycles and cryptands |
| title_full_unstemmed | Self-assembled xanthate-transition metal polyether macrocycles and cryptands |
| title_short | Self-assembled xanthate-transition metal polyether macrocycles and cryptands |
| title_sort | self assembled xanthate transition metal polyether macrocycles and cryptands |
| work_keys_str_mv | AT beerp selfassembledxanthatetransitionmetalpolyethermacrocyclesandcryptands AT cowleya selfassembledxanthatetransitionmetalpolyethermacrocyclesandcryptands AT jefferyj selfassembledxanthatetransitionmetalpolyethermacrocyclesandcryptands AT paulr selfassembledxanthatetransitionmetalpolyethermacrocyclesandcryptands AT wongw selfassembledxanthatetransitionmetalpolyethermacrocyclesandcryptands |