Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes.
Self-focusing of intense microwave radiation at the tip of a 25 microm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM(+)PF(6)(-)) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric...
Main Authors: | , , , , |
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Format: | Journal article |
Language: | English |
Published: |
2004
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_version_ | 1797094014218928128 |
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author | Sur, UK Marken, F Coles, B Compton, R Dupont, J |
author_facet | Sur, UK Marken, F Coles, B Compton, R Dupont, J |
author_sort | Sur, UK |
collection | OXFORD |
description | Self-focusing of intense microwave radiation at the tip of a 25 microm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM(+)PF(6)(-)) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K (at the electrode surface)--extreme conditions sufficient for condensed phase pyrolysis processes to occur. |
first_indexed | 2024-03-07T04:08:16Z |
format | Journal article |
id | oxford-uuid:c6f486da-0197-44f3-9704-126ef27d7323 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T04:08:16Z |
publishDate | 2004 |
record_format | dspace |
spelling | oxford-uuid:c6f486da-0197-44f3-9704-126ef27d73232022-03-27T06:41:35ZMicrowave activation in ionic liquids induces high temperature-high speed electrochemical processes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c6f486da-0197-44f3-9704-126ef27d7323EnglishSymplectic Elements at Oxford2004Sur, UKMarken, FColes, BCompton, RDupont, JSelf-focusing of intense microwave radiation at the tip of a 25 microm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM(+)PF(6)(-)) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K (at the electrode surface)--extreme conditions sufficient for condensed phase pyrolysis processes to occur. |
spellingShingle | Sur, UK Marken, F Coles, B Compton, R Dupont, J Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes. |
title | Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes. |
title_full | Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes. |
title_fullStr | Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes. |
title_full_unstemmed | Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes. |
title_short | Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes. |
title_sort | microwave activation in ionic liquids induces high temperature high speed electrochemical processes |
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