Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes.

Self-focusing of intense microwave radiation at the tip of a 25 microm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM(+)PF(6)(-)) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric...

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Main Authors: Sur, UK, Marken, F, Coles, B, Compton, R, Dupont, J
Format: Journal article
Language:English
Published: 2004
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author Sur, UK
Marken, F
Coles, B
Compton, R
Dupont, J
author_facet Sur, UK
Marken, F
Coles, B
Compton, R
Dupont, J
author_sort Sur, UK
collection OXFORD
description Self-focusing of intense microwave radiation at the tip of a 25 microm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM(+)PF(6)(-)) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K (at the electrode surface)--extreme conditions sufficient for condensed phase pyrolysis processes to occur.
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spelling oxford-uuid:c6f486da-0197-44f3-9704-126ef27d73232022-03-27T06:41:35ZMicrowave activation in ionic liquids induces high temperature-high speed electrochemical processes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c6f486da-0197-44f3-9704-126ef27d7323EnglishSymplectic Elements at Oxford2004Sur, UKMarken, FColes, BCompton, RDupont, JSelf-focusing of intense microwave radiation at the tip of a 25 microm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM(+)PF(6)(-)) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K (at the electrode surface)--extreme conditions sufficient for condensed phase pyrolysis processes to occur.
spellingShingle Sur, UK
Marken, F
Coles, B
Compton, R
Dupont, J
Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes.
title Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes.
title_full Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes.
title_fullStr Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes.
title_full_unstemmed Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes.
title_short Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes.
title_sort microwave activation in ionic liquids induces high temperature high speed electrochemical processes
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AT markenf microwaveactivationinionicliquidsinduceshightemperaturehighspeedelectrochemicalprocesses
AT colesb microwaveactivationinionicliquidsinduceshightemperaturehighspeedelectrochemicalprocesses
AT comptonr microwaveactivationinionicliquidsinduceshightemperaturehighspeedelectrochemicalprocesses
AT dupontj microwaveactivationinionicliquidsinduceshightemperaturehighspeedelectrochemicalprocesses