Halide abstraction by Na[B{C6H3(CF3)(2)-3,5}4]: Synthesis and structural characterization of the rhodium(I) cations [(eta(6)-arene)Rh(PPh3)(2)](+) (arene = benzene, toluene)
Halide abstraction from [(Ph3P)2Rh(μ-Cl)] 2 by the sodium salt of the weakly coordinating [BArf4]- anion [Arf = C6H 3(CF3)2-3,5] in the presence of excess arene offers a convenient, high-yielding route to the half-sandwich cations [(arene)Rh(PPh3)2]+[BArf4]- [arene = benzene (1), toluene (2)]. Cryst...
| Main Authors: | , , , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2006
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