Influence of ligand backbone flexibility in group 4 metal complexes of tetradentate mixed tertiary amine/alkoxide ligands
Simple epoxide ring opening chemistry using the cyclic secondary amine 1,4-diazacycloheptane or the related linear species N,N′- dimethylethylenediamine, and racemic (±)-3,3-dimethyl-1,2-epoxybutane gives access to the pendant alcohol functionalised ditertiary amine pro-ligands [HOCH(tBu)CH2N(R)CH2]...
| Autores principales: | , , , , , , , |
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| Formato: | Journal article |
| Lenguaje: | English |
| Publicado: |
2007
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