Enantioselective synthesis of non-biaryl atropisomers

Enantioselective synthesis of non-biaryl atropisomers

<p>This thesis describes the development of novel methods to synthesise non-biaryl atropisomers enantioselectively. In Chapter 1, atropisomerism is defined and explored, with a focus on non-biaryl atropisomers and the literature stereoselective syntheses of chiral naphthamides. Chapter 2 discu...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awdur:	Fugard, A
Awduron Eraill:	Smith, M
Fformat:	Traethawd Ymchwil
Iaith:	English
Cyhoeddwyd:	2019
Pynciau:	Chemistry, Organic

Eitemau Tebyg

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Carbamate-directed benzylic lithiation for the diastereo- and enantioselective synthesis of diaryl ether atropisomers
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The enantioselective total synthesis of Sealutomicin C
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Carbene-catalyzed asymmetric construction of atropisomers
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Structural studies on biaryl phosphines and palladium complexes composed of biaryl phosphines
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New cation-mediated enantioselective transformations and catalytic enantioselective photocyclization
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Development of new methods in tetrahydropyran ring synthesis : application to enantioselective synthesis of natural products
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New catalytic strategies for the enantioselective synthesis of stereogenic-at-phosphorus(V) compounds
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Catalytic enantioselective synthesis of atropisomeric biaryls by a cation-directed O-alkylation
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Electrochemical Organic Synthesis of Electron-Rich Biaryl Scaffolds: An Update
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Enantioselective Steglich rearrangement catalysed by chiral guanidinium ion pairs
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Phosphoramidite ligand design for the enantioselective conjugate addition of alkylzirconium reagents to enones
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Bisguanidiums catalyzed enantioselective oxidation of sulfides to sulfoxides
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Rhodium-catalysed regio- and enantioselective Suzuki-Miyaura cross-coupling reactions
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Enantioselective addition of diphenylphosphine to 3-methyl-4-nitro-5-alkenylisoxazoles
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Primary amines as heterogeneous catalysts in an enantioselective [2,3]-Wittig rearrangement reaction
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Enantioselective construction of ortho-sulfur- or nitrogen-substituted axially chiral biaryls and asymmetric synthesis of isoplagiochin D
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Cobalt-catalyzed enantioselective directed C-H alkylation of indole with styrenes
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Highly atroposelective synthesis of nonbiaryl naphthalene-1,2-diamine N-C atropisomers through direct enantioselective C-H amination
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Cyhoeddwyd: (2019-07-01)

Copper-catalyzed enantioselective conjugate addition of grignard reagents to methyl 4,4,4-trifluorocrotonate : synthesis of enantioenriched trifluoromethylated compounds
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Organocatalytic enantioselective γ-aminoalkylation of unsaturated ester : access to pipecolic acid derivatives
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Enantioselective Stetter reactions of enals and modified chalcones catalyzed by N-heterocyclic carbenes
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Part I: Design of chiral indium complexes for enantioselective carbon-carbon bond formation reactions. Part II: Synthetic studies towards the total synthesis of RK-397
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Interrogating the configurational stability of atropisomers
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Cyhoeddwyd: (2023)

Phenanthrene synthesis via chromium-catalyzed annulation of 2-biaryl grignard reagents and alkynes
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Enantioselective total Synthesis of the agelastatin and trigonoliimine alkaloids
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Cyhoeddwyd: (2012)

Enantioselective Diels–Alder reactions of enals and alkylidene diketones catalyzed by N-heterocyclic carbenes
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Cyhoeddwyd: (2014)

Carbene-catalyzed [4 + 2] cycloadditions of vinyl enolate and (in situ generated) imines for enantioselective synthesis of quaternary α-amino phosphonates
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Asymmetric synthesis of N-benzyl-5-methylhydroxy-piperidone and modular synthesis of C1-substituent tetrahydroisoquinolines (THIQ) and C2-symmetric bisisoquinolines (C2-BIQ) and their catalytic application in enantioselective Henry reaction
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Cyhoeddwyd: (2015)